127808-17-7Relevant academic research and scientific papers
UN EQUIVALENT SYNTHETIQUE CHIRAL DU PRENAL, LE FORMYL-TRIMETHYLENEMETHANE(FER)TRICARBONYLE. SYNTHESE DU (R)-(-)-IPSDIENOL
Franck-Neumann, Michel,Martina, Daniel,Heitz, Marie-Paule
, p. 6679 - 6682 (1989)
Formyl-TMM (Iron)tricarbonyl 3 reacts with a high diastereoselectivity with organozinc derivatives to Iron stabilized TMM-alcohols.These are decomplexed, under partial hydrogenation, by photolysis in acetic acid to give allylic and homoallylic isoprenoic alcohols.Starting from the optically active complex (+)-3, this allows a rapid synthesis of (R)-(-)-Ipsdienol of high ee.
