53198-44-0Relevant academic research and scientific papers
Cyclic α-acetoxynitrosamines: Mechanisms of decomposition and stability of α-hydroxynitrosamine and nitrosiminium ion reactive intermediates
Chahoua, Latifa,Cai, Hongliang,Fishbein, James C.
, p. 5161 - 5169 (2007/10/03)
A study of the kinetics and mechanism of the decay of α-acetoxy-N- nitrosopyrrolidine and α-acetoxy-N-nitrosopiperidine are reported. The compounds differ in reactivity by more than 2 orders of magnitude at physiological pH. On the basis of thermodynamic
The Chemistry of Nitrosamines, IV. - Syntheses of α-C-Functionalized N-Nitrosodialkylamines: Esters and Ethers of 1-alcohols
Mueller, Eduard,Kettler, Regina,Wiessler, Manfred
, p. 1468 - 1493 (2007/10/02)
Imines (Schiff's bases) and nitrosyl chloride react to give N-alkyl-1-chloro-N-nitrosoalkylamines 13.Nucleophilic substitution by acetate or p-nitrobenzoate affords the acetates 7 and 9 and p-nitrobenzoates 8 and 10, respectively.The spectroscopic and chemical data of the newly synthesized compounds are discussed.
