53206-65-8

Upstream product

• 870-63-3 prenyl bromide 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 2881-83-6 ethyl 4-methoxybenzoylacetate 
• 34499-34-8 ethyl 2-(4-methoxybenzoyl)-5-methylhex-4-enoate 
• 1642593-79-0 C₁₄H₂₀O₂ 
• 123-11-5 4-methoxy-benzaldehyde 
• 2270-59-9 1-bromo-4-methylpent-3-ene 

Downstream Products

• 863092-91-5 ethyl 3-(4-methoxyphenyl)-7-methyl-octa-2,6-dienoate 
• 17171-17-4 4'-methoxy-3-methylbiphenyl 
• 1642593-64-3 1-(4-methoxyphenyl)-4,4-dimethyl-2,3-dioxabicyclo[3.2.1]octane 
• 100572-79-0 1-Methoxy-4-(5-methyl-1-methylen-4-hexenyl)benzol 
• 223691-88-1 1-(1,5-dimethyl-1-vinyl-hex-4-enyl)-4-methoxy-benzene 
• 850406-02-9 2-(4-methoxyphenyl)-2,6-dimethylhept-5-enal 
• 863092-93-7 ethyl 3-(4-methoxyphenyl)-7-methyl-3-vinyl-oct-6-enoate 
• 863092-99-3 3-(4-methoxy-phenyl)-7-methyl-3-vinyl-oct-6-en-1-ol 
• 863092-92-6 3-(4-methoxyphenyl)-7-methyl-octa-2,6-dien-1-ol 

Relevant academic research and scientific papers

Radical Aza-Cyclization of α-Imino-oxy Acids for Synthesis of Alkene-Containing N-Heterocycles via Dual Cobaloxime and Photoredox Catalysis

Nitrogen-containing heterocycles are prevalent in both naturally and synthetically bioactive molecules. We report herein an unprecedented protocol for radical aza-cyclization of α-imino-oxy acids with pendant alkenes via synergistic photoredox and cobaloxime catalysis. With or without alkenes as the intermolecular cross-coupling partners, the transformation provides a variety of corresponding alkene-containing dihydropyrrole products in satisfactory yields. In the presence of external alkenes, the tandem reaction generates E-selective coupling products with excellent chemo- and stereoselectivity.

Cyclization-endoperoxidation cascade reactions of dienes mediated by a pyrylium photoredox catalyst

Triarylpyrylium salts were employed as single electron photooxidants to catalyze a cyclization-endoperoxidation cascade of dienes. The transformation is presumed to proceed via the intermediacy of diene cation radicals. The nature of the diene component was investigated in this context to determine the structural requirements necessary for successful reactivity. Several unique endoperoxide structures were synthesized in yields up to 79%.

Synthesis of biaryls via AlCl3 catalyzed domino reaction involving cyclization, dehydration, and oxidation

A new chemical access has been developed to synthesize biaryls from substituted acetophenones, phenylacetones, dihydrochalcone, and 2-acetylnaphthalene in reasonably good yields at room temperature via a domino reaction sequence of AlCl3 catalyzed cyclization, dehydration, and then oxidation.

Synthesis of sporochnol A, a marine fish deterrent

A synthesis of the methyl ether of the fish-deterrent sporochnol A is described. The route involves the application of Claisen ortho-ester rearrangement to generate the key quaternary carbon. Copyright Taylor & Francis, Inc.