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Methyl trichloromethyl sulfone, also known as MTS, is a chemical compound with the molecular formula C2H3Cl3O2S. It is a colorless to pale yellow liquid with a pungent odor and is soluble in organic solvents. MTS is primarily used as a chemical intermediate in the synthesis of various pharmaceuticals, agrochemicals, and other specialty chemicals. It is also employed as a reagent in organic synthesis, particularly in the preparation of sulfonamides and sulfonate esters. Due to its reactivity and potential toxicity, MTS requires careful handling and storage to ensure safety and minimize environmental impact.

5324-44-7

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5324-44-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 5324-44-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,3,2 and 4 respectively; the second part has 2 digits, 4 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 5324-44:
(6*5)+(5*3)+(4*2)+(3*4)+(2*4)+(1*4)=77
77 % 10 = 7
So 5324-44-7 is a valid CAS Registry Number.

5324-44-7Relevant academic research and scientific papers

α,β-unsaturated α′-halomethylsulfones: Prepackaged Ramberg-Baecklund reagents for tandem synthetic processes

Block, Eric,Hak, Rim Jeon,Putman, David,Zhang, Shao-Zhong

, p. 1197 - 1202 (2005)

The synthesis and reactions of several α,β-unsaturated chloromethyl sulfones are presented, for example [(chloromethyl) sulfonyl]-1,3-propadiene, [(chloromethyl) sulfonyl]ethene, [(dichloromethyl) sulfonyl]ethene and (E,Z)-1,2-bis[(chloromethyl)-sulfonyl]ethene. These compounds serve as prepackaged Ramberg-Backlund reagents, which, following an appropriate first step, such as Diels-Alder addition, react with a base, giving Ramberg-Backlund products. Copyright Taylor & Francis Inc.

Chloromethanesulfonylethene and Dichloromethanesulfonylethene: New Reagents for Tandem Diels-Alder/Ramberg-Baecklund Reactions

Block, Eric,Jeon, Hak Rim,Zhang, Shao-Zhong,Dikarev, Evgeny V.

, p. 437 - 440 (2007/10/03)

(Matrix presented) Chloromethanesulfonylethene (3a) and dichloromethanesulfonylethene (3b) were prepared by oxidation of the adducts of ethylene and ClCH2-SCl or Cl2CHSCl, respectively, followed by NaHCO3 dehydrochlorinati

Prepackaged Ramberg-B?cklund reagents: Useful tools for organic synthesis

Block, Eric,Jeon, Hak Rim,Putman, David,Zhang, Shao-Zhong

, p. 7525 - 7541 (2007/10/03)

The synthesis and reactions of several α,β-unsaturated chloromethyl sulfones is presented, for example [(chloromethyl)sulfonyl]-1,3- propadiene (4), [(chloromethyl)sulfonyl]ethene (5), [(dichloromethyl)sulfonyl] ethene (6) and (E,Z)-1,2-bis[(chloromethyl)

Mechanism in the chlorinolysis of sulfinyl chlorides

Ahern, Terence Patrick,Haley, Michael Francis,Langler, Richard Francis,Trenholm, June Ellen

, p. 610 - 614 (2007/10/02)

The successful synthesis and chlorinolysis of α-mercaptodimethyl sulfone have provided additional support for our contention that Pummerer rearrangements may occur during the chlorinolyses of α-sulfonyl sulfinyl chlorides.Further exploration of chlorinolyses of α-sulfonyl systems has uncovered the first observation of CS bond cleavage during the chlorinolyses of (i) a sulfinyl chloride and (ii) a sulfinate ester.

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