53243-71-3

Upstream product

• 90-02-8 salicylaldehyde 
• 100-36-7 N,N-diethylethylenediamine 

Downstream Products

• 105084-37-5 {Pt(OC₆H₄CHNCH₂CH₂N(C₂H₅)2)(P(C₆H₅)3)}⁽¹⁺⁾ 
• 105096-20-6 Pt⁽²⁺⁾*OC₆H₄CHNCH₂CH₂N(C₂H₅)2^(1-)*SCN^(1-)={Pt(OC₆H₄CHNCH₂CH₂N(C₂H₅)2)(SCN)} 
• 105084-35-3 {Pt(OC₆H₄CHNCH₂CH₂N(C₂H₅)2)(As(C₆H₅)3)}⁽¹⁺⁾ 
• 384842-70-0 2-[[2-(diethylamino)-ethylamino]methyl]phenol 

Relevant academic research and scientific papers

Newly designed Mn (III)–W(V) bimetallic assembly built by manganese (III) Schiff–base and octacyanotungstate(V) building blocks: Structural topologies, and magnetic features

New complex [Mn (SB)2(DMF)2] [W (CN)8] hereafter referred to as complex 1, which was prepared by self–assembly of [Mn (SB)2(DMF)2]3+ and [W (CN)8]3? and structurally c

Copper(II) azide complexes with NNO donor ligands: Syntheses, structure, catalysis and biological studies

Three copper(II) tridentate (NNO) Schiff base azido complexes, [Cu(L 1)(N3)] (1), [Cu2(L2) 2(μ2-1,1-N3)2] [Cu(L 2)(N3)] (2) and [Cu(L3

p-Toluate-bridged dinuclear Cu(II) complexes in combination with tridentate chelating ligand: Crystal structure, density functional theory calculation, DNA/protein binding and catecholase activity

The dinuclear Cu(II) complexes [Cu2(L1)2(mb)]?ClO4 (1) and [Cu2(L2)2(mb)]?ClO4 (2) (HL1?=?2-[(2-diethylaminoethylimino)methyl]phenol; HL2?=?2-[1-

Studies on the influence of the nuclearity of zinc(ii) hemi-salen complexes on some pivotal biological applications

Though a large amount of literature has been reported on outlining the biological significance of zinc(ii) Schiff base complexes, yet none of them have explored the influence of nuclearity on their properties. This report elaborates the targeted syntheses

Synthesis and characterization of three new photo-luminescent cadmium(II) complexes with azide: Variation in molecular structures with changes in the denticity of blocking ligands

Three new cadmium(II) complexes, [Cd(dede)(μ-1,3-N3)(μ-1,1-N3)]n (1), [{Cd3(L1)2(μ-1,1-N3)4(CH3OH)2}·2CH3OH·2H2O]n/su

Variation in molecular and crystalline architectures of di- and poly-nuclear cadmium(II) complexes on changing the denticity of the blocking ligands

Three cadmium(II) complexes, [Cd(dmpn)(μ-1,1-N3) 2]n (1), [Cd(L1)2Cd(N 3)2] (2) and [Cd2(L2) 2(Cl)2] (3) {where dmpn is a bidentate ch

Solvomorphism and catecholase activities of bis(μ-phenoxido) dicopper(II) complexes

Two phenoxido bridged dinuclear Cu(II) complexes, [Cu2(L 1)2(NCO)2] (1), and [Cu2(L 2)2(NCO)2]·2CH3OH (2), have been synthesized using the tridentate reduced Schiff-base ligands 2-[(2-dimethylamino-ethylamino)-methyl]-phenol (HL1) and 2-[(2-diethylamino-ethylamino)-methyl]-phenol (HL2) respectively. Re-crystallization of compound 2 from dichloromethane produced desolvated complex [Cu2(L2)2(NCO)2] (3). The compounds 2 and 3 are pseudopolymorphs or solvomorphs which differ in the crystal system (orthorhombic, Pbca for 2 and monoclinic, P21/n for 3). The complexes have been characterized by X-ray structural analyses and spectroscopic methods. In all three complexes Cu(II) is penta-coordinated having the geometry intermediate between distorted square pyramid and trigonal bipyramid with Addison parameter (τ) = 0.33, 0.48 and 0.53 for 1, 2 and 3 respectively. Using 3,5-di-tert-butylcatechol (3,5-DTBC) as the substrate, the catecholase activity of complexes 1 and 2 has been studied in methanol solution; compound 2 shows slightly higher catecholase activity (kcat = 98.4h 1) than compound 1 (kcat = 64.2 h 1).

X-Ray Structures and Spectral Properties of 4-Coordinate Copper(II) and Palladium(II) Complexes with Tridentate ONN-Schiff Base Ligand

The tridentate mono-basic Schiff base N-(2-diethylaminoethyl)salicylaldimine Hsal-en-NEt2 forms complexes 1 = with divalent metals M (Y = halide).The preparation of three copper(II) complexes 1a (Y = Br), 1b (Y = Cl), and 1c (Y = SCN) and one palladium(II) complex 1d (Y = Cl) is described and the UV/VIS spectra of these complexes in methanol and chloroform are compared and discussed.The crystals of 1a*CHCl3, 1b*CHCl3, and 1d*CHCl3 are all isotypic and crystallize in the orthorhombic space group Pbca, whereas the solvent-free crystals of 1b (and also 1a) are monoclinic with the space group P21/c.The metal is 4-coordinate with an almost planar ONNY donor atom arrangement around the palladium and with a distorted arrangement around the copper.The crystals consist of separate non-bridged complex units and the chloroform is not coordinated. - Keywords: X-ray, UV/VIS Spectra, Tridentate ONN Schiff Base, Copper(II) Complexes, Palladium(II) Complexes