53312-53-1Relevant academic research and scientific papers
Synthesis of the tricyclic core of aldingenin b by oxidative cyclo ketalization of an alkyne-diol
Yang, Jingyue,Tummatorn, Jumreang,Slegeris, Rimantas,Tlais, Sami F.,Dudley, Gregory B.
, p. 2065 - 2067 (2011)
The preparation and selenium-mediated cyclo-ketalization of an alkyne-diol is described as a model study for the synthesis of aldingenin B. The oxidative cyclization is a simplifying transformation for aldingenin B, as it provides a convenient method for
73. Synthesis of (+)-(4S,8R)-8-Epi- and (-)-(4R,8S)-4-Epi-β-bisabolol
Frater, Georg,Mueller, Urs
, p. 653 - 658 (2007/10/02)
The first total enantioselective synthesis of (+)-(4S,8R)-8-epi-β-bisabolol ((+)-1) and of (-)-(4R,8S)-4-epi-β-bisabolol ((-)-1) is reported.The key step in the synthesis is the kinetic resolution of (+-)-5 by means of the Sharpless epoxidation yielding (
