5337-28-0

Basic information

• Product Name: (1Z)-2-(biphenyl-4-yl)-N-hydroxy-2-oxoethanimidoyl chloride
• CAS NO: 5337-28-0
• Molecular Formula: C₁₄H₁₀ClNO₂
• Molecular Weight: 259.6877
• Mol File: 5337-28-0.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 453.951°C at 760 mmHg
• Flash Point: 228.342°C
• Density: 1.239g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.596
• CAS DataBase Reference: (1Z)-2-(biphenyl-4-yl)-N-hydroxy-2-oxoethanimidoyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: (1Z)-2-(biphenyl-4-yl)-N-hydroxy-2-oxoethanimidoyl chloride(5337-28-0)
• EPA Substance Registry System: (1Z)-2-(biphenyl-4-yl)-N-hydroxy-2-oxoethanimidoyl chloride(5337-28-0)

Safety Data

• Hazardous Substances Data: 5337-28-0(Hazardous Substances Data)

Usage

General Description

(1Z)-2-(biphenyl-4-yl)-N-hydroxy-2-oxoethanimidoyl chloride, also known as BPCl, is a chemical compound with the molecular formula C14H10ClNO2. It is a derivative of biphenyl and is commonly used in the field of organic synthesis. BPCl is an imidoyl chloride, which is a class of compounds known for their reactivity towards various nucleophiles. It is a key intermediate in the synthesis of various pharmaceuticals and agrochemicals, and it is also used as a building block for the preparation of other organic molecules. BPCl has potential applications in medicinal chemistry and as a reagent in organic synthesis, making it an important chemical in the field of chemical research and development.

Upstream product

• 635-84-7 4-(chloroacetyl)biphenyl 

Downstream Products

• 1295503-60-4 4-(2-hydroxo-5-chlorophenylaminoisonitrosoacetyl)biphenyl 
• 947254-06-0 2-(biphenyl-4-yl)-N-(4-chlorophenyl)-N'-hydroxy-2-oxoacetimidamide 
• 947254-05-9 2-(biphenyl-4-yl)-N'-hydroxy-N-(4-methylphenyl)-2-oxoacetimidamide 
• 110826-96-5 (p-phenylphenyl)ethanolamine 

Relevant articles and documents

Synthesis of (2-hydroxo-5-chlorophenylaminoisonitrosoacetyl)phenyl ligands and their complexes: Spectral, thermal and solvent-extraction studies

Four different types of new ligands Ar[COC(NOH)R] n (Ar=biphenyl, n = 1 H2L1; Ar=biphenyl, n = 2 H 4L2; Ar=diphenylmethane, n = 1 H2L3; Ar=diphenylmethane, n = 2 H4L4; R=2-amino-4-chlorophenol in all ligands) have been obtained from 1 equivalent of chloroketooximes Ar[COC(NOH)Cl] n (HL1-H2L4) and 1 equivalent of 2-amino-4-chlorophenol (for H2L1 and H 2L3) or 2 equivalent of 2-amino-4-chlorophenol (for H 4L2 and H4L4). (Mononuclear or binuclear cobalt(II), nickel(II), copper(II) and zinc(II) complexes were synthesized with these ligands.) These compounds have been characterized by elemental analyses, AAS, infra-red spectra and magnetic susceptibility measurements. The ligands have been further characterized by 1H NMR. The results suggest that the dinuclear complexes of H2L1 and H2L3 have a metal:ligand ratio of 1:2; the mononuclear complexes of H4L2 and H4L4 have a metal:ligand ratio of 1:1 and dinuclear complexes H4L2 and H4L4 have a metal:ligand ratio of 2:1. The binding properties of the ligands towards selected transition metal ions (Mn II, CoII, NiII, CuII, Zn II, PbII, CdII, HgII) have been established by extraction experiments. The ligands show strong binding ability towards mercury(II) ion. In addition, the thermal decomposition of some complexes is studied in nitrogen atmosphere.