5339-02-6

Basic information

• Product Name: N,N-dimethyl-4-[(1E)-non-1-en-1-yl]aniline
• CAS NO: 5339-02-6
• Molecular Formula: C₁₇H₂₇N
• Molecular Weight: 245.403
• Mol File: 5339-02-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 361.7°C at 760 mmHg
• Flash Point: 146.9°C
• Density: 0.917g/cm³
• Vapor Pressure: 2.04E-05mmHg at 25°C
• Refractive Index: 1.542
• CAS DataBase Reference: N,N-dimethyl-4-[(1E)-non-1-en-1-yl]aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethyl-4-[(1E)-non-1-en-1-yl]aniline(5339-02-6)
• EPA Substance Registry System: N,N-dimethyl-4-[(1E)-non-1-en-1-yl]aniline(5339-02-6)

Safety Data

• Hazardous Substances Data: 5339-02-6(Hazardous Substances Data)

Upstream product

• 100-10-7 4-dimethylamino-benzaldehyde 
• 44767-62-6 n-hexylmagnesium chloride 
• 20850-05-9 (E)-3-{4-(N,N-dimethylamino)phenyl}prop-2-en-1-ol 

Relevant articles and documents

Nickel-Catalyzed Alkylation or Reduction of Allylic Alcohols with Alkyl Grignard Reagents

By choosing different phosphine ligands, nickel-catalyzed selective alkylation and reduction of allylic alcohols with alkyl Grignard reagents were performed. The reaction using Ni(dppe)Cl2 as the catalyst resulted in the cross-coupling of allylic alcohols with primary alkyl Grignard reagents and cyclopropylmagnesium bromide. The reaction catalyzed by the combination of Ni(PCy3)2Cl2 and dcype led to the reduction of allylic alcohols. Secondary alkyl Grignard reagents except cyclopropylmagnesium bromide always led to reduction of allylic alcohols using either Ni(dppe)Cl2 or Ni(PCy3)2Cl2/dcype as the catalyst. In the reductive reaction β-H-containing alkyl Grignard reagents were required.