53392-15-7

Basic information

• Product Name: 1,4-Methanopentalen-3(2H)-one,hexahydro-
• CAS NO: 53392-15-7
• Molecular Weight: 136.194
• Mol File: 53392-15-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,4-Methanopentalen-3(2H)-one,hexahydro- (CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Methanopentalen-3(2H)-one,hexahydro- (53392-15-7)
• EPA Substance Registry System: 1,4-Methanopentalen-3(2H)-one,hexahydro- (53392-15-7)

Safety Data

• Hazardous Substances Data: 53392-15-7(Hazardous Substances Data)

Upstream product

• 3048-65-5 cis-bicyclo<4.3.0>nona-3,7-diene 
• 127-08-2 potassium acetate 
• 56170-01-5 cis-bicyclo<4.3.0>nona-2,7-diene 
• 64-19-7 acetic acid 
• 3048-65-5 cis-bicyclo<4.3.0>nona-3,7-diene 

Downstream Products

• 105961-55-5 Z-oxime of brexan-5-one 
• 105961-55-5 E-oxime of brexan-5-one 
• 3104-87-8 brexane 
• 3104-87-8 brendan-2-one 
• 77787-42-9 endo-brexan-5-ol p-bromobenzenesulfonate 
• 80878-22-4 5-phenyl-4-brexene 

Relevant articles and documents

ISOMERIC CIS-BICYCLONONADIENES

cis-Bicyclonona-2,7-dienes and the corresponding 2,8-dienes were obtained by the isomerization of cis-bicyclonona-3,7-diene and dehydration of the cis-bicyclonon-7(8)-en-3-ols.The 13C and PMR spectra of the isomeric dienes were investigated, and their retention times in GLC analysis were determined.The reaction of cis-bicyclonona-3,7-diene with N-bromosuccinimide in aqueous DMSO and the reaction of cis-bicyclonona-2,7-diene with acetic acid were studied.

ADDITION OF ORGANIC ACIDS TO cis-BICYCLONONA-3,7-DIENE. SYNTHESIS OF COMPOUNDS OF THE BREXANE AND BRENDANE SERIES

The esters of cis-bicyclononenols, exo- and endo-brexan-5-ols, and exo-brendan-2-ol were obtained by the addition of formic, acetic, and trifluoroacetic acids to cis-bicyclonona-3,7-diene.The composition of the reaction products and its dependence on the reaction conditions were determined.A method is proposed for the separation of the bicyclic and tricyclic components.The mechanism of the transannular cyclization is discussed.