5340-80-7

Basic information

• Product Name: 5-tert-butylnonan-5-ol
• CAS NO: 5340-80-7
• Molecular Formula: C₁₃H₂₈O
• Molecular Weight: 200.3608
• Mol File: 5340-80-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 234.5°C at 760 mmHg
• Flash Point: 97.6°C
• Density: 0.832g/cm³
• Vapor Pressure: 0.00969mmHg at 25°C
• Refractive Index: 1.442
• CAS DataBase Reference: 5-tert-butylnonan-5-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-tert-butylnonan-5-ol(5340-80-7)
• EPA Substance Registry System: 5-tert-butylnonan-5-ol(5340-80-7)

Safety Data

• Hazardous Substances Data: 5340-80-7(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 598-98-1 Methyl pivalate 
• 3938-95-2 2,2-dimethyl-propanoic acid ethyl ester 
• 3282-30-2 pivaloyl chloride 
• 75-98-9 Trimethylacetic acid 
• 502-56-7 nonanone-5 
• 594-19-4 tert.-butyl lithium 
• 106-98-9 1-butylene 
• 37490-37-2 2-tert.-Butyl-4,5-benzo-1,3,2-dioxaborol 
• 693-03-8 n-butyl magnesium bromide 

Downstream Products

• 55705-76-5 4-Nitro-benzoic acid 1-butyl-1-tert-butyl-pentyl ester 

Relevant articles and documents

Effets de cryptands et activation de bases. VI. Reactions d'organo-lithiens.

Utilization of the cryptand shows the need of electrophilic catalysis by the Li(1+) ion in the nucleophilic addition of organolithium compounds to ketones, esters, or carboxylic acids.When nucleophilic addition is inhibited, organolithium reagents enolyze ketones or esters.When activated by cryptation of Li(1+), organolithium reagents attack ethers in a few minutes.With alkyl halides, only elimination takes place: exchange and nucleophilic substitution are not observed any longer in the presence of the cryptand.Generally speaking, the cryptand seems to enhance the basicity of the organolithium reagent, and nucleophilicity does not manifest itself any more.