53429-51-9Relevant academic research and scientific papers
One-pot synthesis of α-acyloxycarbonyl compounds via oxidative decarboxylation coupling reaction of α-oxo carboxylic acids with carbonyl compounds
Chang, Li-Ming,Yuan, Gao-Qing
, p. 7003 - 7007 (2016/10/13)
With tetrabutylammonium iodide (TBAI) as the catalyst and tert-butyl hydroperoxide (TBHP) as the oxidant, a simple metal-free protocol has been developed for the synthesis of α-acyloxycarbonyl compounds from carbonyl compounds and α-oxo carboxylic acids via decarboxylative coupling reaction. The target products could be obtained in moderate to high yields.
A general method for the α-acyloxylation of carbonyl compounds
Beshara, Cory S.,Hall, Adrian,Jenkins, Robert L.,Jones, Kerri L.,Jones, Teyrnon C.,Killeen, Niall M.,Taylor, Paul H.,Thomas, Stephen P.,Tomkinson, Nicholas C. O.
, p. 5729 - 5732 (2007/10/03)
(Chemical Equation Presented) A simple, one-pot method for the α-acyloxylation of carbonyl compounds that proceeds at room temperature in the presence of both moisture and air has been developed. Treatment of a variety of aldehydes and both cyclic and acy
Reaction of Enol Silyl Ethers with Silver Carboxylate-Iodine. Synthesis of α-Acyloxy Carbonyl Compounds
Rubottom, George M.,Mott, Robert C.,Juve, Henrik D.
, p. 2717 - 2721 (2007/10/02)
The sequential treatment of enol silyl ethers with silver carboxylate-iodine (2:1) and then fluoride affords high yields of the corresponding α-acyloxy carbonyl compounds.Thus a wide range of variation is now possible for the acyloxy portion of the molecu
