53581-92-3Relevant academic research and scientific papers
A rapid and highly efficient Michael addition of methoxybenzenes and indoles to α,β-unsaturated ketones using BF3·OEt2 as a catalyst
Swetha,Raghavender Reddy,Madhu Babu,Meshram
supporting information, p. 4427 - 4431 (2017/10/30)
An efficient and general protocol is described for the Michael addition of α,β-unsaturated ketones with electron-rich arenes/indoles to give alkylated arenes/indoles under mild reaction condition at room temperature. Shorter reaction time, convenient and
Heterobimetallic Pd-Sn catalysis: Michael addition reaction with C-, N-, O-, and S-nucleophiles and in situ diagnostics
Das, Debjit,Pratihar, Sanjay,Roy, Sujit
supporting information, p. 2430 - 2442 (2013/04/23)
An efficient Michael addition reaction of differently substituted enones with carbon, sulfur, oxygen, and nitrogen nucleophiles has been achieved by a new heterobimetallic "Pd-Sn" catalyst system. The nature of the catalytically relevant species and their
Addition of heterocycles to electron deficient olefins and alkynes catalyzed by gold(III)
Li, Zigang,Shi, Zhangjie,He, Chuan
, p. 5049 - 5054 (2007/10/03)
A gold(III)-catalyzed hydroarylation of different olefins is reported here. AuCl3 works as an excellent catalyst to mediate reactions between various heterocycles and electron deficient olefins and alkynes under mild conditions. This gold(III)-based method tolerates different functional groups such as aldehyde, carboxylic acid, nitrile, and is highly efficient. We have shown that some of these reactions complete in minutes at room temperature.
Gold(III) Chloride-Catalyzed Addition Reactions of Electron-Rich Arenes to Methyl Vinyl Ketone
Dyker, Gerald,Muth, Enrico,Hashmi, A. Stephen K.,Ding, Li
, p. 1247 - 1252 (2007/10/03)
For the reaction of α,β-unsaturated ketones with electron-rich arenes catalyzed by gold(III) chloride both, a Friedel-Crafts-type mechanism and an initial metallation, are evaluated. Gold(III) chloride has proven to be an efficient catalyst under very mod
