53585-13-0

Basic information

• Product Name: Cyclohexene, 4-(1,5-dimethyl-4-hexenylidene)-1-methyl-, (4E)-
• CAS NO: 53585-13-0
• Molecular Formula: C15H24
• Molecular Weight: 204.356
• Mol File: 53585-13-0.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 4-(1,5-dimethyl-4-hexenylidene)-1-methyl-, (4E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 4-(1,5-dimethyl-4-hexenylidene)-1-methyl-, (4E)-(53585-13-0)
• EPA Substance Registry System: Cyclohexene, 4-(1,5-dimethyl-4-hexenylidene)-1-methyl-, (4E)-(53585-13-0)

Safety Data

• Hazardous Substances Data: 53585-13-0(Hazardous Substances Data)

Upstream product

• 372-97-4 farnesyl pyrophosphate 
• 40716-66-3 (E)-3,7,11-trimethyl-1,6,10-dodecatrien-3-ol 
• 53585-12-9 4-methyl-1-(1'-propanalethylidene)-3-cyclohexene 
• 24470-78-8 isopropyltriphenylphosphonium iodide 
• 515-69-5 bisabolol 
• 106-28-5 Farnesol 
• 106131-34-4 (E)-3-(tert-Butyl-dimethyl-silanyloxy)-3,7,11-trimethyl-6-trimethylsilanyl-dodeca-1,6,10-triene 
• 106131-32-2 (2Z,6E)-1-(tert-Butyl-dimethyl-silanyloxy)-3,7,11-trimethyl-6-trimethylsilanyl-dodeca-2,6,10-triene 
• 106131-36-6 3-Oxo-7-trimethylsilanyl-hept-6-ynoic acid methyl ester 
• 106131-38-8 (Z)-3-Methyl-7-trimethylsilanyl-hept-2-en-6-ynoic acid methyl ester 
• 106131-33-3 tert-Butyl-dimethyl-(1-methyl-1-vinyl-pent-4-ynyloxy)-silane 
• 106131-30-0 tert-Butyl-dimethyl-((Z)-3-methyl-hept-2-en-6-ynyloxy)-silane 
• 106131-39-9 (2Z)-3-methylhept-2-en-6-yn-1-ol 
• 370565-23-4 (2Z)-2-allyl-3,7-dimethyl-2,6-octadien-1-ol 

Relevant articles and documents

(E)-γ-BISABOLEN-8,9-EPOXIDE AND ISOCYCLOEUDESMOL, TWO NEW SESQUITERPENOIDS FROM THE MARINE RED ALGA LAURENCIA NIPPONICA YAMADA

Two new sesquiterpenoids, (E)-γ-bisabolen-8,9-epoxide and isocycloeudesmol, have been isolated from L. nipponica Yamada (Rhodophyta, Rhodomelaceae) and their structures have been determined by spectroscopic and chemical evidences.

Isotope sensitive branching and kinetic isotope effects to analyse multiproduct terpenoid synthases from Zea mays

Multiproduct terpene synthases TPS4-B73 and TPS5-Delprim from Zea mays exhibit isotopically sensitive branching in the formation of mono- and sesquiterpene volatiles. The impact of the kinetic isotope effects and the stabilization of the reactive intermediates by hyperconjugation along with the shift of products from alkenes to alcohols are discussed.

Stereoselective synthesis of exocyclic alkenes by Cu-catalyzed allylmagnesiation, Pd-catalyzed alkylation, and Ru-catalyzed ring-closing metathesis: Highly stereoselective synthesis of (Z)- and (E)-γ-bisabolenes

Highly efficient stereoselective syntheses of both (Z)- and (E)-γ-bisabolenes (1) were achieved by ring closing metathesis of stereodefined tetrasubstituted alkenes. Both (Z)- and (E)-tetrasubstituted alkene precursors were obtained by Cu-catalyzed stereoselective addition of allylmagnesium bromide to propargyl alcohols, followed by Pd-catalyzed cross coupling of alkylzinc derivatives. This represents the first application of ring-closing metathesis to the stereoselective synthesis of exocyclic alkenes.