53587-73-8Relevant academic research and scientific papers
Synthesis of trisubstituted alkenes by reductive dehydroxylation of Baylis-Hillman adducts using polymethylhydrosiloxane (PMHS) and catalytic B(C6F5)3
Chandrasekhar,Chandrashekar,Vijeender,Reddy, M. Srinivasa
, p. 3475 - 3478 (2006)
B(C6F5)3 as a catalyst and polymethylhydrosiloxane as a hydride source have been employed for the reductive dehydroxylation of Baylis-Hillman adducts wherein the hydride adds in an SN2′ manner onto the unactivat
Palladium catalysed regio and stereoselective reduction of Baylis- Hillman coupling products derived allylic acetates
Pachamuthu, Kandaswamy,Vankar, Yashwant D.
, p. 5439 - 5442 (2007/10/03)
Acetates derived from a variety of the Baylis-Hillman products undergo reduction with HCOOH in the presence of Et3N, Pd(OAc)2, and dppe (or tri- isopropylphosphite) to yield the corresponding trisubstituted Z-olefins in good yields d
