535994-33-3Relevant academic research and scientific papers
Cu-Catalyzed silylation of alkynes: A traceless 2-pyridylsulfonyl controller allows access to either regioisomer on demand
García-Rubia, Alfonso,Romero-Revilla, Jose A.,Mauleón, Pablo,Gómez Arrayás, Ramón,Carretero, Juan C.
supporting information, p. 6857 - 6865 (2015/06/16)
The Cu-catalyzed silylation of terminal and internal alkynes bearing a 2-pyridyl sulfonyl group (SO2Py) at the propargylic position affords a breadth of vinyl silanes in good yields and with excellent regio- and stereocontrol under mild conditi
Enantio- and diastereoselective synthesis of cyclic β-hydroxy allylsilanes via sequential aldehyde γ-silylallylboration and ring-closing metathesis reactions
Heo, Jung-Nyoung,Micalizio, Glenn C.,Roush, William R.
, p. 1693 - 1696 (2007/10/03)
(Matrix presented) Highly enantioenriched cyclic allylsilanes are prepared via stereoselective γ-silylallylboration reactions of β- or γ-unsaturated aldehydes followed by ring-closing metathesis.
