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(+/-)-cis-2-phenoxy-cyclopropanecarbonitrile is a chemical compound with the molecular formula C??H?NO. It is a chiral molecule, meaning it has two enantiomeric forms, (+) and (-), which are mirror images of each other. The compound features a cyclopropane ring, a three-carbon ring structure, with a phenoxy group (a phenol derivative) and a cyano group (-CN) attached to the second carbon atom. This unique structure gives it potential applications in various fields, such as pharmaceuticals and agrochemicals, due to its ability to interact with biological targets. However, it is important to note that the specific uses and effects of (+/-)-cis-2-phenoxy-cyclopropanecarbonitrile would depend on its enantiomeric form, as the (+) and (-) forms may have different biological activities.

5362-45-8

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5362-45-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 5362-45-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,3,6 and 2 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 5362-45:
(6*5)+(5*3)+(4*6)+(3*2)+(2*4)+(1*5)=88
88 % 10 = 8
So 5362-45-8 is a valid CAS Registry Number.

5362-45-8Relevant academic research and scientific papers

Highly Diastereo- and Enantioselective Synthesis of Nitrile-Substituted Cyclopropanes by Myoglobin-Mediated Carbene Transfer Catalysis

Chandgude, Ajay L.,Fasan, Rudi

supporting information, p. 15852 - 15856 (2018/11/23)

A chemobiocatalytic strategy for the highly stereoselective synthesis of nitrile-substituted cyclopropanes is reported. The present approach relies on an asymmetric olefin cyclopropanation reaction catalyzed by an engineered myoglobin in the presence of ex situ generated diazoacetonitrile within a compartmentalized reaction system. This method enabled the efficient transformation of a broad range of olefin substrates at a preparative scale with up to 99.9 % de and ee and up to 5600 turnovers. The enzymatic product could be further elaborated to afford a variety of functionalized chiral cyclopropanes. This work expands the range of synthetically valuable, abiotic transformations accessible through biocatalysis and paves the way to the practical and safe exploitation of diazoacetonitrile in biocatalytic carbene transfer reactions.

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