766-94-9

Basic information

• Product Name: phenyl vinyl ether
• Synonyms: Ethenyloxybenzene;Phenoxyethene;Phenoxyethylene;Vinyl phenyl ether;Phenyl vinyl ether 97%
• CAS NO: 766-94-9
• Molecular Formula: C₈H₈O
• Molecular Weight: 120.15
• Mol File: 766-94-9.mol
• Article Data: 42

Chemical Properties

• Boiling Point: 155.5°C (estimate)
• Flash Point: 16℃
• Appearance: /
• Density: 0.978 g/mL at 25 °C(lit.)
• Vapor Pressure: 3.87mmHg at 25°C
• Refractive Index: n20/D1.522(lit.)
• Storage Temp.: 2-8°C
• CAS DataBase Reference: phenyl vinyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl vinyl ether(766-94-9)
• EPA Substance Registry System: phenyl vinyl ether(766-94-9)

Safety Data

• Hazard Codes: F,Xn
• Statements: 11-22-43-51
• Safety Statements: 36/37
• RIDADR: UN 3271 3 / PGII
• WGK Germany: 3
• Hazardous Substances Data: 766-94-9(Hazardous Substances Data)

Usage

General Description

Phenyl vinyl ether is a chemical compound with the molecular formula C8H8O. It is an organic compound that is typically used as a monomer in the production of polymers and copolymers. Phenyl vinyl ether is a clear, colorless liquid with a sweet, pleasant odor. It is highly flammable and should be handled with caution. phenyl vinyl ether is also used as a solvent in organic synthesis and as a precursor in the production of other organic compounds. Phenyl vinyl ether can undergo polymerization and can be used in the production of adhesives, coatings, and plastics. Additionally, it is a valuable intermediate for the synthesis of pharmaceuticals and agrochemicals.

InChI:InChI=1/C8H8O/c1-2-9-8-6-4-3-5-7-8/h2-7H,1H2

Upstream product

• 75-01-4 chloroethylene 
• 139-02-6 sodium phenoxide 
• 37137-00-1 1-iodo-2-phenoxy-ethane 
• 19981-17-0 sodium cyanamide 
• 74-86-2 acetylene 
• 108-95-2 phenol 
• 7732-18-5 water 
• 137325-64-5 diethyl-methyl-(2-phenoxy-ethyl)-ammonium; iodide 
• 64-17-5 ethanol 
• 108-05-4 vinyl acetate 
• 4279-76-9 phenoxyacetylene 
• 67-68-5 dimethyl sulfoxide 
• 57169-70-7 C₁₄H₁₄OSe 
• 614-73-3 1-ethoxy-2-iodobenzene 

Downstream Products

• 882-21-3 phenyl-(1,3,3,3-tetrachloro-propyl)-ether 
• 106165-16-6 acetaldehyde-(sec-butyl-phenyl-acetal) 
• 85642-12-2 acetic acid-(1-phenoxy-ethyl ester) 
• 74-86-2 acetylene 
• 108-95-2 phenol 
• 106165-17-7 acetaldehyde-(tert-butyl-phenyl-acetal) 
• 20682-70-6 1-(n-butoxy-1-phenoxy)ethane 
• 4850-74-2 bisphenoxyethane 
• 1441-03-8 (+/-)-(1,4,5,6,7,7-hexachloro-norborn-5-ene-2endo-yl)-phenyl ether 
• 62359-74-4 1-Brom-1-fluor-2-phenoxy-cyclopropan 
• 90920-26-6 2,2,2-Trichlor-1-hydroxy-1'-phenoxy-diaethylaether 
• 37150-69-9 (2-Cyclohexylidene-cyclopropoxy)-benzene 
• 10446-25-0 1-Phenoxy-1--aethan 
• 1441-03-8 1,2,3,4,7,7-Hexachlor-5-phenoxy-bicyclo<2,2,1>hepten-(2) 

Relevant articles and documents

The phenyl vinyl ether–methanol complex: A model system for quantum chemistry benchmarking

The structure of the isolated aggregate of phenyl vinyl ether and methanol is studied by combining a multi-spectroscopic approach and quantum-chemical calculations in order to investigate the delicate interplay of noncovalent interactions. The complementa

Synthesis of vinyl phenyl ether and its use for ammetric titration of silver(I)

Catalytic vinylation of phenol with acetylene at atmospheric pressure was studied. The yield of vinyl phenyl ether was determined as influenced by the solvent, reaction temperature, and catalyst amount. The mechanism of formation of vinyl phenyl ether was proposed. Ammetric titration of silver(I) with a solution of vinyl phenyl ether in nonaqueous acetic acid solutions was performed.

Reusable rhodium catalyst for the selective transvinylation of sp2-C linked carboxylic acid

The vinyl benzoate derivatives were successfully synthesized by the transvinylation reactions that vinyl group transferred from vinyl acetate to aromatic carboxylic acids with the recoverable catalyst RhCl3·3H2O. This catalyst features air stable and tolerance of water, good reusable ability, meanwhile, shows high selectivity for aromatic carboxylic acid in the presence of phenolic hydroxyl. With this method, a variety of vinyl benzoate derivatives can be produced with up to 95% yield.

Direct vinylation of natural alcohols and derivatives with calcium carbide

Vinyl ethers are essential synthetic building blocks for organic synthesis, especially for polymer synthesis and highly vinylated polyol substrates. Herein, a transition metal-free, mild, and safe protocol has been developed for direct vinylation of natural alcohols with calcium carbide. Various sugar alcohols, phenol and its derivatives were tested and proved successful using this green methodology. Selectivity of full vinylated products of the reaction decreases with increasing hydroxyl groups because of side reactions occurring under the basic medium. Electron-donating substituted phenols work more efficiently than electron-withdrawing substituted phenols in general. This methodology may provide new insights on selective vinylation of electron-rich biomass-derived materials.