53635-52-2

Basic information

• Product Name: Ethanethioic acid, bromo-, S-(1,1-dimethylethyl) ester
• CAS NO: 53635-52-2
• Molecular Formula: C6H11BrOS
• Molecular Weight: 211.123
• Mol File: 53635-52-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanethioic acid, bromo-, S-(1,1-dimethylethyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanethioic acid, bromo-, S-(1,1-dimethylethyl) ester(53635-52-2)
• EPA Substance Registry System: Ethanethioic acid, bromo-, S-(1,1-dimethylethyl) ester(53635-52-2)

Safety Data

• Hazardous Substances Data: 53635-52-2(Hazardous Substances Data)

Upstream product

• 75-66-1 2-methylpropan-2-thiol 
• 64-19-7 acetic acid 

Downstream Products

• 121638-49-1 (2R^*,3S^*)-2,3-epoxy-3-(2,3-dimethoxyphenyl)-t-butylthiopropanoate 
• 121638-44-6 (2R^*,3R^*)-2-bromo-3-hydroxy-3-(2,3-dimethoxyphenyl)-t-butylthiopropanoate 
• 135923-78-3 (4-tert-Butyl-cyclohex-1-enyl)-thioacetic acid S-tert-butyl ester 
• 135923-77-2 (4-tert-Butyl-cyclohexylidene)-thioacetic acid S-tert-butyl ester 
• 135923-81-8 (2E,4E)-5-Phenyl-penta-2,4-dienethioic acid S-tert-butyl ester 
• 63877-27-0 Cyclohexylidene-thioacetic acid S-tert-butyl ester 
• 112303-67-0 S-tert-butyl (3R)-3-hydroxy-3-phenylpropanethioate 
• 142528-81-2 S-tert-Butyl 3-cyclohexyloxirane-2-carbothioate 
• 121638-42-4 (2R^*,3R^*)-2-bromo-3-hydroxy-3-(2-methoxyphenyl)-t-butylthiopropanoate 
• 121638-48-0 (2R^*,3S^*)-2,3-epoxy-3(2-methoxyphenyl)-t-butylthiopropanoate 
• 121638-43-5 (2R^*,3R^*)-2-bromo-3-hydroxy-3-(2-methylphenyl)-t-butylthiopropanoate 
• 121673-24-3 (2R^*,3S^*)-2,3-epoxy-3(2-methylphenyl)-t-butylthiopropanoate 
• 163881-61-6 (2S,3S)-2-Bromo-3-hydroxy-3-phenyl-thiopropionic acid S-tert-butyl ester 
• 142528-88-9 S-tert-Butyl 4-cyclohexyl-1-oxaspiro<2.5>octane-2-carbothioate 

Relevant articles and documents

A convenient procedure for the conversion of carboxylic acids to α-bromo thiolesters

Carboxylic acids can be conveniently transformed to the corresponding α-bromo thiolesters by a one-pot procedure involving Hell-Volhard-Zelinsky reaction and trapping the α-bromo acyl bromide intermediate with mercaptans.