5364-87-4

Basic information

• Product Name: Cyclohexanol, 1,4,4-trimethyl-
• Synonyms: Cyclohexanol, 1,4,4-trimethyl-
• CAS NO: 5364-87-4
• Molecular Formula: C9H18O
• Molecular Weight: 142.241
• Mol File: 5364-87-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 1,4,4-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 1,4,4-trimethyl-(5364-87-4)
• EPA Substance Registry System: Cyclohexanol, 1,4,4-trimethyl-(5364-87-4)

Safety Data

• Hazardous Substances Data: 5364-87-4(Hazardous Substances Data)

Upstream product

• 24463-33-0 4-dichloromethyl-4-methyl-cyclohexanone 
• 6611-78-5 4-dichloromethyl-4-methyl-2,5-cyclohexadienone 
• 75-16-1 methylmagnesium bromide 
• 4255-62-3 4,4-dimethylcyclohexane-1-one 
• 861574-93-8 4-dichloromethyl-1,4-dimethyl-cyclohexanol 

Downstream Products

• 7094-27-1 1,1,4-trimethylcyclohexane 
• 13145-50-1 1,4,4-Trimethyl-cyclohexylchlorid 
• 3419-71-4 1,4,4-trimethyl-1-cyclohexene 

Relevant articles and documents

Photoinduced Fragmentation Borylation of Cyclic Alcohols and Hemiacetals

A visible-light photoinduced fragmentation borylation of O-phthalimido cycloalkanols with bis(catecholato)diboron is described. Structurally diverse keto and formyloxy alkyl boronic esters are shown to be conveniently prepared by radical-mediated ring opening of cyclic alcohols and hemiacetals, respectively. The reactions proceed under mild conditions in the absence of additives or photocatalysts, display excellent functional group tolerance, and are shown to allow cleavage of 4-, 5-, 6-, and 7-membered ring substrates. The mechanism proceeds via sequential homolytic N-O and C-C bond cleavages, the latter of which involves β-scission of an alkoxy radical, generating a carbonyl and an alkyl radical that is trapped by the diboron reagent. Spectroscopic studies suggest direct photoexcitation of either the phthalimide or diboron substrates with blue light can initiate a radical chain mechanism.