53724-05-3

Basic information

• Product Name: 2-Propyn-1-one, 1-cyclohexyl-3-(trimethylsilyl)-
• CAS NO: 53724-05-3
• Molecular Formula: C12H20OSi
• Molecular Weight: 208.376
• Mol File: 53724-05-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-Propyn-1-one, 1-cyclohexyl-3-(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propyn-1-one, 1-cyclohexyl-3-(trimethylsilyl)-(53724-05-3)
• EPA Substance Registry System: 2-Propyn-1-one, 1-cyclohexyl-3-(trimethylsilyl)-(53724-05-3)

Safety Data

• Hazardous Substances Data: 53724-05-3(Hazardous Substances Data)

Upstream product

• 54655-07-1 lithium trimethylsilylacetylenide 
• 80783-98-8 N-methoxy-N-methylcyclohexanecarboxamide 
• 133216-88-3 (+/-)-1-cyclohexyl-3-(trimethylsilyl)-2-propynol 
• 2043-61-0 cyclohexanecarbaldehyde 
• 1066-54-2 trimethylsilylacetylene 
• 2719-27-9 cyclohexanylcarbonyl chloride 
• 98-89-5 Cyclohexanecarboxylic acid 
• 132539-51-6 (3-cyclohexylprop-1-ynyl)trimethylsilane 
• 14630-40-1 Bis(trimethylsilyl)ethyne 

Downstream Products

• 950758-23-3 (2-cyclohexyl-1,3-dithiolan-2-ylethynyl)-trimethylsilane 
• 244191-29-5 C₃₂H₄₄Si₂ 
• 1237786-79-6 (S)-hexa-1,5-dien-3-ylcyclohexane 
• 1378870-78-0 (R)-hex-5-en-1-yn-3-ylcyclohexane 
• 108104-21-8 (S)-1-cyclohexyl-2-propyn-1-ol acetate 
• 53724-07-5 (2,2-Bis-trimethylsilyl-vinyl)-cyclohexylketon 
• 127618-31-9 (E)-1-cyclohexyl-3-methoxyprop-2-en-1-one 
• 105880-38-4 (1S)-1-cyclohexyl-2-propyn-1-ol 
• 950758-19-7 2-cyclohexyl-2-hex-1-ynyl-1,3-dithiolane 
• 920979-34-6 2-cyclohexyl-2-ethynyl-1,3-dithiolane 
• 950758-01-7 7-cyclohexyl-7-(hydroxyisopropyl)-8,11-dithiapentadec-5-yne 
• 950758-00-6 7-cyclohexyl-7-(α-hydroxybenzyl)-8,11-dithiapentadec-5-yne 
• 950757-99-0 7-cyclohexyl-7-(1-hydroxyisopropyl)-8,11-dithiapentadec-5-yne 
• 244191-28-4 trifluoro-methanesulfonic acid 1-cyclohexylidene-3-trimethylsilanyl-prop-2-ynyl ester 

Relevant articles and documents

Enantioselective Inverse Electron Demand (3 + 2) Cycloaddition of Palladium-Oxyallyl Enabled by a Hydrogen-Bond-Donating Ligand

Cycloaddition reactions between oxyallyl cations and alkenes are important transformations for the construction of ring systems. Although (4 + 3) cycloaddition reactions of oxyallyl cations are well-developed, (3 + 2) cycloadditions remain rare, and an as

Mild propargylic oxidation using a diacetoxyiodobenzene/tert-butyl hydroperoxide protocol

A mild propargylic oxidation of alkynes is reported using a diacetoxyiodobenzene/tert-butyl hydroperoxide (DIB/TBHP) protocol. The reactions proceed smoothly at 0 °C and a number of α,β-unsaturated alkynoic ketones are obtained.

meso-Phbox-Pd(II) catalyzed tandem carbonylative cyclization of 1-ethynyl-1-propargyl acetate

Palladium(II) catalyzed carbonylation of 1-ethynyl-1-propargyl acetate 1 is described; in the absence of the bisoxazoline (box) ligand, the second triple bond did not react, affording cyclic orthoesters 3 and 4. The use of meso-Phbox-Pd(II) strikingly changed the course of the reaction, yielding bicyclic lactone 2 by tandem carbonylative cyclization as a result of insertion of the second triple bond. The Royal Society of Chemistry.