537657-55-9Relevant academic research and scientific papers
Neutral and dianionic organoantimony(III) dithiolene complexes: Syntheses, x-ray crystal structures, and unexpected reactivity
Avarvari, Narcis,Fourmigue, Marc
, p. 2042 - 2049 (2003)
The new neutral PhSb(dmid) (dmid2- = 4,5-dithiolato-1,3-dithiol-2-one) complexes has been synthesized upon reaction of deprotected 1,3,4,6-tetrathiapentalene-2,5-dione with dichlorophenylstibine. Single-crystal X-ray structure determination shows an original three-dimensional network in the solid state, via Sb- - -O and Sb- - -S secondary interactions, based on an octagonal Sb4S4 motif. Not only PhSb(dmid) but also PhSb(dmit) (dmit2- = 4,5-dithiolato-1,3-dithiole-2-thione) reacts with a second 1 equiv of dithiolate to give a series of highly reactive dianionic complexes, unknown so far. One of these complexes, [Me4N]2[PhSb(dmid)2], was structurally characterized by single-crystal X-ray measurements. Both dithiolene ligands, lying in the equatorial plane of a distorted octahedron, are unsymmetrically coordinated, with two Sb-s distances much longer than the other two. These dianionic species reacted with 1 equiv of PhSbCl2 to give unexpectedly, a series of Sb(V) [Ph2Sb(dithiolene)2]- complexes. The same compounds were obtained directly upon slow addition of 1 equiv of PhSbCl2 on the corresponding dithiolate suspensions. This demonstrates that dianionic [PhSbIII(dithiolene)2]2- species are key intermediates in the synthesis of [Ph2SbV(dithiolene)2]- salts. The single-crystal X-ray structure determination of the tetraethylammonium salts of [Ph2Sb(dmid)2]-, [Ph2Sb(dmit)2]-, and [Ph2Sb(dmid)(dmit)]- show a distorted-octahedral coordination geometry for the Sb center with a cis configuration of the phenyl groups. This is preserved also in solution, as established by 13 NMR. Using the same technique, combined with 1H NMR, in a scrambling experiment, a fast dithiolene exchange has been emphasized. In the case of the [Ph2Sb(dmid)2]- salt, two polymorphs, with different folding angles along the S - S hinge, were crystallized.
