537658-28-9

Upstream product

• 5927-18-4 trimethyl phosphonoacetate 
• 537658-39-2 (E)-2-Benzyloxymethyl-4-oxo-but-2-enoic acid (1S,2S)-2-(tert-butyl-dimethyl-silanyloxy)-1,2-diphenyl-ethyl ester 
• 537658-26-7 (2E,4E)-2-Benzyloxymethyl-5-phenyl-penta-2,4-dienoic acid (1S,2S)-2-(tert-butyl-dimethyl-silanyloxy)-1,2-diphenyl-ethyl ester 
• 537658-19-8 (2E,4E)-2-Hydroxymethyl-5-phenyl-penta-2,4-dienoic acid methyl ester 
• 124957-46-6 (2E,4E)-methyl 2-acetoxymethyl-5-phenyl-penta-2,4-dienoate 
• 100-39-0 benzyl bromide 
• 537658-21-2 (2E,4E)-2-Benzyloxymethyl-5-phenyl-penta-2,4-dienoic acid methyl ester 

Downstream Products

• 537658-37-0 C₃₀H₃₈O₅S₂ 
• 537658-32-5 C₃₁H₃₈O₆S₂ 
• 537658-33-6 C₃₁H₄₀O₆S₂ 
• 537658-35-8 C₃₁H₄₂O₆S₂ 
• 537658-29-0 C₅₆H₅₆O₇S₂Si 
• 537658-16-5 (2E,4E)-2-Benzyloxymethyl-hexa-2,4-dienedioic acid 1-((1S,2S)-2-hydroxy-1,2-diphenyl-ethyl) ester 6-methyl ester 

Relevant academic research and scientific papers

Progress toward the total synthesis of (+)-aldosterone: synthesis of the A-D rings.

[reaction: see text] Synthesis of the A-D rings of the cortical hormone (+)-aldosterone is described. The key step incorporates a chiral tether in a type 2 intramolecular Diels-Alder reaction that establishes the absolute configuration of four contiguous