53778-56-6Relevant academic research and scientific papers
Palladium-Catalyzed Intramolecular Cyanosilylation of Alkynes Leading to Stereoselective Synthesis of α,β-Unsaturated Nitriles
Suginome, Michinori,Kinugasa, Hiroshi,Ito, Yoshihiko
, p. 8635 - 8638 (2007/10/02)
Intramolecular cyanosilylation was achieved by the reaction of chlorodiphenylsilyl ether of homopropargylic alcohols with trimethylsilylcyanide in the presence of palladium catalyst. The reaction proceeded regio- and stereoselectively to give (Z)-3-(1-cya
The Stereochemistry of Organometallic Compounds. XXXI Hydrocyanation of Alkynols
Jackson, W. Roy,Lovel, Craig G.,Perlmutter, Patrick,Smallridge, Andrew J.
, p. 1099 - 1106 (2007/10/02)
The regioselectivity of hydrocyanation of a range of alkynols using nickel-based catalyst systems involving either triphenyl phosphite or α,α'-bis(diphenylphosphino)-o-xylene (phmep) has been investigated.The regioselectivity of the hydrocyanations involv
