53786-93-9Relevant articles and documents
Catalytic Enantioselective Hetero-dimerization of Acrylates and 1,3-Dienes
Jing, Stanley M.,Balasanthiran, Vagulejan,Pagar, Vinayak,Gallucci, Judith C.,RajanBabu
supporting information, p. 18034 - 18043 (2017/12/26)
1,3-Dienes are ubiquitous and easily synthesized starting materials for organic synthesis, and alkyl acrylates are among the most abundant and cheapest feedstock carbon sources. A practical, highly enantioselective union of these two readily available pre
Cobalt-catalyzed asymmetric hydrovinylation
Vogt, Dieter
scheme or table, p. 7166 - 7168 (2010/12/19)
(Chemical equation presented) Back to the first row: A surprisingly simple protocol involving chiral diphosphine complexes of cobalt(II) salts allows the highly enantioselective hydrovinylation of 1,3-dienes in extremely high selectivities and yields.