5381-37-3

Basic information

• Product Name: Benzene, (2,2,3-trimethylcyclopropyl)-, cis-
• CAS NO: 5381-37-3
• Molecular Formula: C12H16
• Molecular Weight: 160.259
• Mol File: 5381-37-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, (2,2,3-trimethylcyclopropyl)-, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2,2,3-trimethylcyclopropyl)-, cis-(5381-37-3)
• EPA Substance Registry System: Benzene, (2,2,3-trimethylcyclopropyl)-, cis-(5381-37-3)

Safety Data

• Hazardous Substances Data: 5381-37-3(Hazardous Substances Data)

Upstream product

• 513-35-9 2-methyl-but-2-ene 
• 618-31-5 benzylidene dibromide 
• 908094-04-2 phenyldiazomethane 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Iron Lewis acid catalyzed reactions of phenyldiazomethane and olefins: Formation of cyclopropanes with very high cis selectivity

The irol Lewis acid, [(η5-C5H5)Fe(CO)2(THF)]+ (1) catalyzes the cyclopropanation reaction of phenyldiazomethane with olefins to provide cis cyclopropanes in high selectivity.

STREREOSPECIFIC CYCLOPROPANE SYNTHESIS FROM γ-STANNYL ALCOHOLS

γ-Stannyl tertiary alcohols and γ-stannyl benzyl alcohols form cyclopropanes strereospecifically on treatment with acid, with inversion of configugation at both carbon atoms.

Reactions of η5-C5H5(CO)2FeCHC6H5+ with Alkenes and Alkynes. Observation of Efficient Benzylidene-Transfer Reactions

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