538335-63-6

Basic information

• Product Name: trans-[Mo2Cp2(μ-η1:η2-CMeCH2)(μ-PCy2)(CO)2]
• CAS NO: 538335-63-6
• Molecular Weight: 616.443
• Mol File: 538335-63-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-[Mo2Cp2(μ-η1:η2-CMeCH2)(μ-PCy2)(CO)2](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[Mo2Cp2(μ-η1:η2-CMeCH2)(μ-PCy2)(CO)2](538335-63-6)
• EPA Substance Registry System: trans-[Mo2Cp2(μ-η1:η2-CMeCH2)(μ-PCy2)(CO)2](538335-63-6)

Safety Data

• Hazardous Substances Data: 538335-63-6(Hazardous Substances Data)

Upstream product

• 537683-53-7 Li[Mo₂Cp₂(μ-PCy₂)(μ-CO)₂] 
• 107-05-1 3-chloroprop-1-ene 

Relevant articles and documents

A versatile and unprecedented triply bonded dimolybdenum carbonyl anion

Chemical reduction of [Mo2Cp2(μ-Cl) (μ-PA2)-(CO)2] (A = Cy, Ph, OEt) gives the corresponding alkaline metal salts of the triply bonded anions [Mo2-Cp2(μ-PA2) (μ-CO)2]-, which exhibit both molybdenum and oxygen nucleophilic sites. The PCy2 anion reacts easily with NH4+, [AuCl(PR3)], or MeI to give unsaturated dicarbonyls [Mo2Cp2(μ-X)(μ-PA2) (CO)2] (X = H, AuPR3, Me), while [Me3O]BF4 gives the methoxycarbyne [Mo2Cp2(μ-COMe)(μ-PCy2)(μ-CO)] and allyl chloride rearranges to give the unsaturated alkenyl complex [Mo2-Cp2(μ-PCy2)(μ-CMeCH2) (CO)2].