53845-29-7Relevant academic research and scientific papers
Switchable Copper-Catalyzed Cascade Synthesis of Thiazolidine-2-thiones and Thiazole-2(3 H)-thiones
Weng, Jian-Quan,Yue, Bin-Jie,Xu, Meng,Yang, Yu-Kun,Jin, Hong-Wei
supporting information, p. 2991 - 2996 (2015/09/28)
A novel copper-catalyzed cascade synthesis of thiazolidine-2-thiones from N-(2-bromoallyl)amines and carbon disulfide has been developed. The procedure combines carbamodithioic acid formation and copper-catalyzed intramolecular S-vinylation in one sequence. By elevating the temperature, the one-pot reaction efficiently affords thiazole-2(3H)-thiones in moderate to good yields.
