53847-13-5Relevant academic research and scientific papers
The formation of cyclic ethers from diallyldibutyltin and halo ketones catalyzed by tetraethylammonium chloride
Yano,Hatta,Baba,Matsuda
, p. 693 - 696 (1992)
The cyclization reaction of diallyldibutyltin and α- or γ-halo ketones, especially chloro-substituted ketones, effectively proceeds in the presence of a catalytic amount of tetraethylammonium chloride, producing the corresponding 2-allyloxiranes or 2-ally
Tandem Anionic oxy-Cope Rearrangement/Oxygenation Reactions as a Versatile Method for Approaching Diverse Scaffolds
?imek, Michal,Bártová, Kate?ina,Císa?ová, Ivana,Jahn, Ullrich,Pohl, Radek
supporting information, p. 6160 - 6165 (2020/03/03)
Tandem anionic oxy-Cope rearrangement/radical oxygenation reactions provide δ,?-unsaturated α-(aminoxy) carbonyl compounds, which serve as convenient precursors to diverse compound classes. Functionalized carbocycles are accessible by very rare all-carbon 5-endo-trig cyclizations, but also common 5-exo-trig radical cyclizations, based on the persistent radical effect. The tandem reactions can be further extended by highly diastereoselective allylation or reduction steps to give complex scaffolds.
Torgov Condensation of Some Vinyl Alcohols
Jayaraman, S.,Rajagopalan, K.
, p. 61 (2007/10/02)
The Torgov condensation of 2-methylcyclopentane-1,3-dione with some vinyl alcohols is reported.
