53967-86-5Relevant academic research and scientific papers
Pyrolysis of aryl azides. XIII*Conformational effects on the ability of carbonyl as a neighbouring group
Dyall, Leonard K.,Ferguson, John A.,Jarman, Tony B.
, p. 1197 - 1202 (2007/10/03)
Our previous claim, 1 that locking an ortho carbonyl group into a favourable conformation causes very large increases in the rate of thermolysis of aryl azides, has been reexamined. In 8-azido-5-methoxy-1-tetralone the rate advantage over an azide with a
Substituent effects on the lifetimes and reactivities of arylnitrenium ions studied by laser flash photolysis and photothermal beam deflection
Robbins, Rebecca J.,Laman, David M.,Falvey, Daniel E.
, p. 8127 - 8135 (2007/10/03)
Photolysis of 5-substituted-N-tert-butyl-3-methylanthranilium ion produces transient N-tert-butyl-(2-acetyl-4-substituted) phenylnitrenium ions. This is confirmed by identification of the stable products, transient absorption experiments, and photothermal
