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54010-75-2

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54010-75-2 Usage

Reaction

Catalyst for the addition of acetylenes to carbonyls and nitrones. Claisen rearrangement. Catalyst for the enantioselective Henry and Aza-Henry reactions. Pd-catalyzed hydroalkylation of styrenes with zinc reagents.

Chemical Properties

white to light-grey powder

Uses

Zinc trifluoromethanesulfonate acts as a catalyst for the preparation of dithioketals. It is used as a Lewis acid catalyst in silylation reactions. It is also used as a catalyst for greener amine synthesis by reductive amination with hydrogen gas.

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Purification Methods

It should be dried at 125o for 2hours at 3mm before use. It is soluble in CH2Cl2 but insoluble in pet ether. [Corey & Shimoji Tetrahedron Lett 24 169 1983.]

Check Digit Verification of cas no

The CAS Registry Mumber 54010-75-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,4,0,1 and 0 respectively; the second part has 2 digits, 7 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 54010-75:
(7*5)+(6*4)+(5*0)+(4*1)+(3*0)+(2*7)+(1*5)=82
82 % 10 = 2
So 54010-75-2 is a valid CAS Registry Number.
InChI:InChI=1/CHF3O3S.Zn/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+2/p-1

54010-75-2 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
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  • Price
  • Detail
  • TCI America

  • (T1294)  Zinc(II) Trifluoromethanesulfonate  >98.0%(T)

  • 54010-75-2

  • 5g

  • 290.00CNY

  • Detail
  • TCI America

  • (T1294)  Zinc(II) Trifluoromethanesulfonate  >98.0%(T)

  • 54010-75-2

  • 25g

  • 775.00CNY

  • Detail
  • Alfa Aesar

  • (L15969)  Zinc trifluoromethanesulfonate, 98%   

  • 54010-75-2

  • 5g

  • 295.0CNY

  • Detail
  • Alfa Aesar

  • (L15969)  Zinc trifluoromethanesulfonate, 98%   

  • 54010-75-2

  • 25g

  • 1036.0CNY

  • Detail
  • Aldrich

  • (290068)  Zinctrifluoromethanesulfonate  98%

  • 54010-75-2

  • 290068-10G

  • 547.56CNY

  • Detail
  • Aldrich

  • (290068)  Zinctrifluoromethanesulfonate  98%

  • 54010-75-2

  • 290068-50G

  • 2,303.73CNY

  • Detail

54010-75-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Zinc trifluoromethanesulfonate

1.2 Other means of identification

Product number -
Other names Zinc triflate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:54010-75-2 SDS

54010-75-2Relevant articles and documents

Structure, dynamics and morphology in the system M(CF3SO3)2 PEOn for M = Zn and Pb

Wendsjoe, Aa.,Lindgren, J.,Paluszkiewicz, C.

, p. 1689 - 1694 (1992)

Ion pairing effects have been studied for M(CF3SO3)2 PEOn films with M = Zn and Pb, and n = 9, 16 and 24. Using FT-ir spectroscopy the SO3 and C-O-C stretching modes for CF3SO3s

Zn(OTf)2-mediated C[sbnd]H activation: An expeditious and solvent-free synthesis of aryl/alkyl substituted quinolines

Sarode, Prashant B.,Bahekar, Sandeep P.,Chandak, Hemant S.

supporting information, p. 5753 - 5756 (2016/12/06)

Zinc(II) triflate catalyzed three-component coupling reactions of alkynes, amines and aldehydes leading to the formation of aryl/alkyl substituted quinolines has been described. Notably, the reaction proceeded efficiently and effectively without the use of ligand, co-catalyst, solvent or inert atmosphere. This robust solvent-free process operates under an ambient atmosphere and avoids the use of precious metals, hazardous solvents and harsh reaction conditions. This atom economic process eliminates the waste generated in the multistep synthesis. Additionally, a pseudo three-component Povarov reaction of amines and butanal proceeds under the same green conditions enabling the formation of 2,3-dialkyl quinolines.

A method of manufacturing a metal salt aminoalkylsulfonic Perfluoropolyalkyl

-

Paragraph 0053, (2016/12/22)

PROBLEM TO BE SOLVED: To provide a method for producing inexpensively and efficiently little-colored organic solvent solution of a metal salt of perfluoroalkyl sulfonic acid. SOLUTION: In this method for producing a metal salt of perfluoroalkyl sulfonic acid represented by general formula (1), a metal oxide is reacted with a perfluoroalkyl sulfonic acid in protonic polar organic solvent capable of dissolving the metal salt of the perfluoroalkyl sulfonic acid. [In the formula, M represents an atom selected from manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn) and rare-earth metals, m represents an integer from 0 to 9, and n represents an integer equal to the valence of M]. COPYRIGHT: (C)2013,JPO&INPIT

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