54043-37-7Relevant academic research and scientific papers
Carbotrifluoromethylation of Allylic Alcohols via 1,2-Aryl Migration Promoted by Visible-Light-Induced Photoredox Catalysis
Cai, Shunyou,Tian, Yu,Zhang, Jinwang,Liu, Zhiji,Lu, Maojian,Weng, Wen,Huang, Mingqiang
, p. 4084 - 4088 (2018)
Visible-light-enabled photocatalytic carbotrifluoro-methylations of allylic alcohols and sodium triflinate were explored through 1,2-migration of an aryl group, affording an efficient method for synthesis of β-trifluoromethyl-α-substituted carbonyl compou
Electrochemical Oxidative Aryl(alkyl)trifluoromethylation of Allyl Alcohols via 1,2-Migration
Guan, Zhipeng,Wang, Huamin,Huang, Yange,Wang, Yunkun,Wang, Shengchun,Lei, Aiwen
supporting information, p. 4619 - 4622 (2019/06/17)
An electrochemical oxidative difunctionalization of allyl alcohols for the synthesis of β-trifluoromethyl ketones is achieved through a 1,2-migration process. A series of β-trifluoromethyl ketones can be facilely obtained utilizing CF3SO2
Iron-catalyzed trifluoromethylation with concomitant C-C bond formation via 1,2-migration of an aryl group
Egami, Hiromichi,Shimizu, Ryo,Usui, Yoshihiko,Sodeoka, Mikiko
supporting information, p. 7346 - 7348 (2013/09/23)
Iron-catalyzed trifluoromethylation with concomitant 1,2-migration of an aryl group starting from diaryl allyl alcohol was achieved under mild conditions. This reaction system affords α-substituted-β- trifluoromethyl carbonyl compounds in high efficiency.
