54061-23-3

Basic information

• Product Name: Benzene, [(2,2-dibromocyclopropyl)thio]-
• CAS NO: 54061-23-3
• Molecular Formula: C9H8Br2S
• Molecular Weight: 308.037
• Mol File: 54061-23-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [(2,2-dibromocyclopropyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2,2-dibromocyclopropyl)thio]-(54061-23-3)
• EPA Substance Registry System: Benzene, [(2,2-dibromocyclopropyl)thio]-(54061-23-3)

Safety Data

• Hazardous Substances Data: 54061-23-3(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 75-25-2 Bromoform 
• 1822-73-7 phenylthioethylene 
• 135226-15-2 dibromocarbene 

Downstream Products

• 78638-79-6 2-methylidene-1-(phenylthio)-1-(trimethylsilyl)cyclopropane 
• 94923-10-1 1-methylidene-2-(phenylsulfinyl)cyclopropane 
• 78656-83-4 1-methylidene-2-(phenylsulfonyl)cyclopropane 
• 78656-80-1 [(2-methylidenecyclopropyl)sulfanyl]benzene 
• 78656-79-8 trans-1-Brom-1-methyl-2-phenylthio-cyclopropan 
• 121820-10-8 1-Bromo-1-lithio-2-(phenylthio)cyclopropanid 
• 54061-26-6 C₁₁H₁₁BrO₂S 

Relevant articles and documents

Observations on some Pd((0)) catalysed intermolecular reaction of electron deficient alkylidene cyclopropanes with olefins: A novel route to highly functionalised skipped diene units

Methylene cyclopropanes 1 bearing an electron withdrawing group react under palladium (0) catalysis with electron poor olefins to give skipped dienes 2. This reaction, which is believed to proceed via hydride transfer, highlights the fact that the reactivity of methylene cyclopropanes can be dramatically influenced by the nature of ring substituents.