540744-15-8Relevant articles and documents
The macrocyclic spermidine alkaloid (-)-(S)-neoperiphylline: Revision of the structure based on the total synthesis
Sergeyev, Sergey A.,Hesse, Manfred
, p. 465 - 473 (2007/10/03)
The total synthesis of the two isomeric macrocyclic enamides 2 and 17 is described. The precursor 14 was synthesized by means of template-assisted macrocyclization (Scheme 2). Isomerization of 14 in the presence of [Fe(CO)5] gave 2 and 17 (Sche