540798-53-6Relevant academic research and scientific papers
Catalytic enantioselective fluorination of α-chloro-β-keto esters in the presence of chiral nickel complexes
Kang, Seung Hee,Kim, Dae Young
, p. 2783 - 2786 (2010)
The catalytic enantioselective electrophilic fluorination promoted by chiral nickel complexes is described. The treatment of α-chloro-β- keto esters with Selectfluor under mild reaction conditions afforded the corresponding fluorinated α-chloro-β-keto est
Recyclable fluorous cinchona alkaloid ester as a chiral promoter for asymmetric fluorination of β-ketoesters
Yi, Wen-Bin,Huang, Xin,Zhang, Zijuan,Zhu, Dian-Rong,Cai, Chun,Zhang, Wei
experimental part, p. 1233 - 1240 (2012/09/21)
A fluorous cinchona alkaloid ester has been developed as a chiral promoter for the asymmetric fluorination of β-ketoesters. It has comparable reactivity and selectivity to the nonfluorous versions of cinchona alkaloids and can be easily recovered from the
