5412-66-8Relevant academic research and scientific papers
Friction modifier and their use in lubricants and fuels
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Page/Page column 29, (2016/01/09)
A non-aqueous lubricating composition containing a major amount of an oil of lubricating viscosity and a minor amount, in the range of 0.02% to 5% by weight, of at least one compound represented by the structural formula (I): wherein R4 represents H or a C1 to C9 hydrocarbyl group or x, y and z are independently integers in the range 1 to 6; and R1, R2 and R3 each independently represent a C1 to C10 hydrocarbyl or substituted hydrocarbyl group.
Method for the synthesis of amine-functionalized fullerenes involving set-promoted photoaddition reactions of -silylamines
Lim, Suk Hyun,Yi, Jinju,Moon, Gyeong Min,Ra, Choon Sup,Nahm, Keepyung,Cho, Dae Won,Kim, Kyungmok,Hyung, Tae Gyung,Yoon, Ung Chan,Lee, Ga Ye,Kim, Soojin,Kim, Jinheung,Mariano, Patrick S.
supporting information, p. 6946 - 6958 (2014/08/18)
A novel method for the preparation of structurally diverse fullerene derivatives, which relies on the use of single electron transfer (SET)-promoted photochemical reactions between fullerene C60 and α-trimethylsilylamines, has been developed. Photoirradiation of 10% EtOH-toluene solutions containing C60 and α-silylamines leads to high-yielding, regioselective formation of 1,2-adducts that arise through a pathway in which sequential SET-desilylation occurs to generate α-amino and C60 anion radical pair intermediates, which undergo C-C bond formation. Protonation of generated α-aminofullerene anions gives rise to formation of monoaddition products that possess functionalized α-aminomethyl-substituted 1,2-dihydrofullerene structures. Observations made in this effort show that the use of EtOH in the solvent mixture is critical for efficient photoproduct formation. In contrast to typical thermal and photochemical strategies devised previously for the preparation of fullerene derivatives, the new photochemical approach takes place under mild conditions and does not require the use of excess amounts of substrates. Thus, the method developed in this study could broaden the scope of fullerene chemistry by providing a simple photochemical strategy for large-scale preparation of highly substituted fullerene derivatives. Finally, the α-aminomethyl-substituted 1,2-dihydrofullerene photoadducts are observed to undergo photoinduced fragmentation reactions to produce C60 and the corresponding N-methylamines.
