5413-59-2Relevant academic research and scientific papers
Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions
Srimani, Dipankar,Balaraman, Ekambaram,Gnanaprakasam, Boopathy,Ben-David, Yehoshoa,Milstein, David
supporting information, p. 2403 - 2406 (2012/11/07)
Cross-dehydrogenative coupling of primary alcohols with secondary alcohols to obtain mixed esters with the liberation of molecular hydrogen is achieved in high yield and good selectivity under neutral conditions, using a bipyridyl-based PNN ruthenium(II) pincer catalyst. Copyright
Ruthenium pincer-catalyzed acylation of alcohols using esters with liberation of hydrogen under neutral conditions
Gnanaprakasam, Boopathy,Ben-David, Yehoshoa,Milstein, David
supporting information; experimental part, p. 3169 - 3173 (2011/02/23)
Acylation of secondary alcohols using non-activated esters, in particular symmetrical esters (such as ethyl acetate), is achieved under neutral conditions with the liberation of molecular hydrogen. This unprecedented, environmentally benign reaction is homogenously catalyzed by a dearomatized ruthenium pincer PNN complex. Copyright
A simple and convenient one-pot synthesis of fatty acid esters from hindered alcohols using N,N-dimethylchloro-sulfitemethaniminium chloride as dehydrating agent
Kaul, Savita,Kumar, Ajay,Sain, Bir,Gupta
, p. 2885 - 2891 (2007/10/03)
N,N-Dimethylchlorosulfitemethaniminium chloride (SOCl2-DMF) has been found to be an efficient reagent for one-pot synthesis of esters from equimolar amounts of fatty acids and hindered alcohols under mild conditions.
Synthesis and Bioevaluation of Alicyclic and Heterocyclic Alkanoates as Cockroach Attractants
Pandey, Karuna Shanker,Mendki, Murlidhar Jaywantrao,Rao, Karumuru Mallikarjuna,Vaidyanathaswamy, Ramamoorthy
, p. 725 - 727 (2007/10/02)
A series of homo and heterocyclic alkanoates were prepared and evaluated as insect attractants toward Blattella germanica (L.) and Supella longipalpa (F.).Among these compounds, the tetrahydrofurfuryl alkanoates and 4-tetrahydropyranyl hexanoate showed relatively better activity.It was also observed that, in general, the five-membered compounds were better performers than their six-membered counterparts.The introdiction of an oxygen atom in the ring enhanced the activity, irrespective of the ring size.
