54193-90-7Relevant academic research and scientific papers
SYNTHESIS OF DISULPHIDES AND TRISULPHIDES via ORGANOSILICON COMPOUNDS
Capozzi, Giuseppe,Capperucci, Antonella,Degl'Innocenti, Alessandro,Duce, Rosa Del,Menichetti, Stefano
, p. 421 - 426 (2007/10/02)
Silyl sulphides 2a-b smoothly react with thiolsulphinates 1a-c and thiolsulphonates 6a-c to give unsymmetrical disulphides under mild conditions and in very good yields.The "neutral" conditions used allow one to avoid any side reactions and subsequent randomization of the products.When bis(trimethylsilyl)sulphide, 8, is used, symmetrical trisulphides may be obtained under the same experimental conditions.
SILICON IN ORGANOSULPHUR CHEMISTRY. Part 2. SYNTHESIS OF UNSYMMETRICAL DISULPHIDES
Capozzi, Giuseppe,Capperucci, Antonella,Degl'Innocenti, Alessandro,Duce, Rosa Del,Menichetti, Stefano
, p. 2995 - 2998 (2007/10/02)
Unsymmetrical aryl- and alkyl-disulphides are prepared from silylsulphides and thiosulphinates or thiosulphonates.Silyl sulphinic esters are also obtained in the reaction of the thiosulphonates.
