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542-50-7

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542-50-7 Usage

Uses

14-Heptacosanone is found in Bulgarian oriental tobacco. It is also isolated from a petroleum ether extract of Styrax officinalis and is used as a growth additive for growing tetragonal prismatic mercuric iodide crystals.

Check Digit Verification of cas no

The CAS Registry Mumber 542-50-7 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,4 and 2 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 542-50:
(5*5)+(4*4)+(3*2)+(2*5)+(1*0)=57
57 % 10 = 7
So 542-50-7 is a valid CAS Registry Number.
InChI:InChI=1/C27H54O/c1-3-5-7-9-11-13-15-17-19-21-23-25-27(28)26-24-22-20-18-16-14-12-10-8-6-4-2/h3-26H2,1-2H3

542-50-7 Well-known Company Product Price

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  • Alfa Aesar

  • (B20191)  14-Heptacosanone, 97%   

  • 542-50-7

  • 5g

  • 549.0CNY

  • Detail
  • Alfa Aesar

  • (B20191)  14-Heptacosanone, 97%   

  • 542-50-7

  • 25g

  • 2380.0CNY

  • Detail

542-50-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 14-Heptacosanone

1.2 Other means of identification

Product number -
Other names heptacosan-14-one

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:542-50-7 SDS

542-50-7Relevant articles and documents

Purification and characterization of OleA from Xanthomonas campestris and demonstration of a non-decarboxylative claisen condensation reaction

Frias, Janice A.,Richman, Jack E.,Erickson, Jasmine S.,Wackett, Lawrence P.

scheme or table, p. 10930 - 10938 (2012/03/26)

OleA catalyzes the condensation of fatty acyl groups in the first step of bacterial long-chain olefin biosynthesis, but the mechanism of the condensation reaction is controversial. In this study, OleA from Xanthomonas campestris was expressed in Escherichia coli and purified to homogeneity. The purified protein was shown to be active with fatty acyl-CoA substrates that ranged from C 8 to C16 in length. With limiting myristoyl-CoA (C 14), 1 mol of the free coenzyme A was released/mol of myristoyl-CoA consumed. Using [14C]myristoyl-CoA, the other products were identified as myristic acid, 2-myristoylmyristic acid, and 14-heptacosanone. 2-Myristoylmyristic acid was indicated to be the physiologically relevant product of OleA in several ways. First, 2-myristoylmyristic acid was the major condensed product in short incubations, but over time, it decreased with the concomitant increase of 14-heptacosanone. Second, synthetic 2-myristoylmyristic acid showed similar decarboxylation kinetics in the absence of OleA. Third, 2-myristoylmyristic acid was shown to be reactive with purified OleC and OleD to generate the olefin 14-heptacosene, a product seen in previous in vivo studies. The decarboxylation product, 14-heptacosanone, did not react with OleC and OleD to produce any demonstrable product. Substantial hydrolysis of fatty acyl-CoA substrates to the corresponding fatty acids was observed, but it is currently unclear if this occurs in vivo. In total, these data are consistent with OleA catalyzing a non-decarboxylative Claisen condensation reactionin the first step of the olefin biosynthetic pathway previously found to be presentin at least 70 different bacterial strains.

Catalytic conversion of C12-C14 primary alcohols mixture into long-chain ketones

Klimkiewicz, Roman,Morawski, Ireneusz,Trawczyński, Janusz

experimental part, p. 1143 - 1147 (2010/11/16)

A charge of raw primary alcohols of high molecular weight from commercial plant was transformed into long-chain ketones fraction of potential commercial use. In this continuous flow method LaMnO3/La-Al2O 3 catalyst was used. At 420 °C and a normal pressure mixture of 74.2 wt.% C12 and 25.8 wt.% C14 primary alcohols and toluene (weight ratio alcohols:toluene = 1:1) was converted into ketones with 73.4% yield in relation to the theoretical value. Ketones were analyzed by TLC, NMR and GC-MSD.

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