54243-60-6Relevant academic research and scientific papers
Order Parameters of β-Substituted Anthraquinone Dyes I: 1-Amino-4-Hydroxyanthraquinone Derivatives
Imazeki, Shuji,Ono, Hitoshi,Kaneko, Masaharu,Mukoh, Akio
, p. 249 - 262 (2007/10/02)
A study is presented of the optical order parameters and spectroscopic properties of 1-amino-4-hydroxyanthraquinone derivatives containing various substituents in the 2-position in a nematic liquid crystalline mixture composed of cyanophenylcyclohexane derivatives.The results are discussed in terms of the effects of the dye structure on the order parameters.By introducing a -SCH2- group into the 2-position, magneta dyes have been obtained which show high order parameters and solubilities.In addition, preliminary data on the solubility and photostability of the dyes are reported.
PHOTOREARRANGEMENT OF 3-ARYLOXYANTHRA-6-ISOXAZOLONES TO NAPHTHOPHENOXAZINE-8,13-DIONES
Dmitriev, F. M.,Gornostaev, L. M.,Gritsan, N. P.,El'tsov, A. V.
, p. 2243 - 2251 (2007/10/02)
3-Aryloxyanthra-6-isoxazolones gives good chemical and quantum yields of the photorearrangement products naphthophenoxazine-8,13-diones, identical with the thermal rearrangement products.The formation of a spiro intermediate was demonstrated.An intermediate particle which changes thermally into the final reaction product was detected.The structure of the intermediate particle was determined by study of the photochemical and subsequent thermal transformations of 3-(2,4,6-trimethylphenoxy)-5-hydroxyanthra-6-isoxazolone.Slow conversion at the nitrogen atom was detected in N-methyl-1,3-dimethylnaphtho phenoxazine-8,13-dione
