54329-03-2Relevant academic research and scientific papers
DIELS-ALDER REACTIONS UNDER MOLECULAR SIEVE CATALYSIS: ENHANCEMENT OF REACTIVITY IN CYCLIZATION REACTIONS WITH N-BENZOYLINDOLE-2,3-QUINODIMETHANE TO FUNCTIONALIZED CARBAZOLES
Pindur, Ulf,Haber, Manfred
, p. 1463 - 1470 (2007/10/02)
In the presence of highly activated molecular sieves (4 Angstroem), the Diels-Alder reactivity of in situ generated N-benzoylindole-2,3-quinomethane is enhanced considerably.Reactions of this species with a variety of carbodienophiles give rise to novel f
3-Halomethylcarbonyl-9-benzoyl-1,2,3,4-tetrahydrocarbazoles
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, (2008/06/13)
Novel 3-Z-9-benzoyl-1,2,3,4-tetrahydrocarbazoles, wherein Z is CONR5 R6, CONHOH, CN, or COCH2 X, where X is chloro or bromo, having antimicrobial and/or anti-inflammatory activity are disclosed. Compounds wherein Z is CONR5 R6 and CONHOH are prepared from the corresponding 3-carboxylic acids by conversion to the corresponding acid chlorides and subsequent reaction with the appropriate amines and hydroxylamine respectively; compounds where Z is CN are prepared by the dehydration of the corresponding compounds where Z is CONH2 ; and the compounds where Z is COCH2 X are prepared by reacting hydrogen chloride or bromide with the corresponding compounds where Z is COCHN2 which in turn is prepared from the corresponding 3-carboxylic acid chloride by reaction with diazomethane.
