5433-44-3Relevant academic research and scientific papers
Electrochemical investigation of some potential antibacterials, II
Jain, Rajeev,Padmaja,Gupta, Seema
, p. 567 - 574 (1997)
The electrochemical behaviour of 2-(4'-sulphonamoyl)hydrazonobutyrate- 1,3-diones and sulphonamoylazoaminobenzenes has been studied over a wide range of pH at dropping mercury as well as glassy carbon electrodes. Both types of compounds exhibited a 4c- reduction reaction at both electrodes. At pH > 4.5; 2-(4'-sulphonamoyl)hydrazonobutyrate-1,3-diones exhibited a 2e- reduction wave at higher potentials. Both compounds undergo a 2e- oxidation reaction. On the basis of polarography, linear and cyclic voltammetry, controlled potential electrolysis, coulometry, and spectral analysis, a detailed mechanism has been postulated for the reduction as well as the oxidation. The electrochemical behaviour of 2-(4′-sulphonamoyl)hydrazonobutyrate-1,3-diones and sulphonamoylazoaminobenzenes has been studied over a wide range of pH at dropping mercury as well as glassy carbon electrodes. Both types of compounds exhibited a 4e- reduction reaction at both electrodes. At pH>4.5, 2-(4′-sulphonamoyl)hydrazonobutyrate-1,3-diones exhibited a 2e- reduction wave at higher potentials. Both compounds undergo a 2e- oxidation reaction. On the basis of polarography, linear and cyclic voltammetry, controlled potential electrolysis, coulometry, and spectral analysis, a detailed mechanism has been postulated for the reduction as well as the oxidation.
