Cas 54353-74-1,Co(1+)*(N(CH2CH2P(C6H5)2)3)*(CO)*B(C6H5)4(1-)=[Co(N(CH2CH2P(C6H5)2)3)(CO)]B(C6H5)4

54353-74-1

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Product Name: Co⁽¹⁺⁾*(N(CH₂CH₂P(C₆H₅)2)3)*(CO)*B(C₆H₅)4^(1-)=[Co(N(CH₂CH₂P(C₆H₅)2)3)(CO)]B(C₆H₅)4
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CAS NO:54353-74-1
Molecular Formula:
Molecular Weight: 1059.96
EINECS: N/A
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Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
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Solubility: N/A
CAS DataBase Reference: Co⁽¹⁺⁾*(N(CH₂CH₂P(C₆H₅)2)3)*(CO)*B(C₆H₅)4^(1-)=[Co(N(CH₂CH₂P(C₆H₅)2)3)(CO)]B(C₆H₅)4(CAS DataBase Reference)
NIST Chemistry Reference: Co⁽¹⁺⁾*(N(CH₂CH₂P(C₆H₅)2)3)*(CO)*B(C₆H₅)4^(1-)=[Co(N(CH₂CH₂P(C₆H₅)2)3)(CO)]B(C₆H₅)4(54353-74-1)
EPA Substance Registry System: Co⁽¹⁺⁾*(N(CH₂CH₂P(C₆H₅)2)3)*(CO)*B(C₆H₅)4^(1-)=[Co(N(CH₂CH₂P(C₆H₅)2)3)(CO)]B(C₆H₅)4(54353-74-1)

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WGK Germany:
RTECS:
HazardClass: N/A
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Hazardous Substances Data: 54353-74-1(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 54353-74-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,4,3,5 and 3 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 54353-74:
(7*5)+(6*4)+(5*3)+(4*5)+(3*3)+(2*7)+(1*4)=121
121 % 10 = 1
So 54353-74-1 is a valid CAS Registry Number.

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54353-74-1Relevant academic research and scientific papers

Synthesis of Novel Mercury(I) Complexes containing a Linear Chain Co-Hg-Hg-Co. X-Ray Crystal Structure of the Complex >2(μ-Hg2)>*thf

Cecconi, Franco,Ghilardi, Carlo A.,Midollini, Stefano,Moneti, Simonetta

, p. 349 - 352 (1983)

Reduction of the cobalt(II) complexes BPh4 with sodium amalgam gives tetrametallic complexes of formula .The structure of 2(μ-Hg2)>*thf was determined from three-dimensional X-ray data collected by the counter method.The crystals are triclinic, space group P1, with a = 25.691(9), b = 13.387(5), c = 13.471(4) Angstroem, α = 119.56(8), β = 97.51(8), γ = 87.25(7) deg, and Z = 2.Full-matrix least-squares refinement converged at the conventional R factor of 0.067 for 2 687 observed reflections.The structure consists of dimeric units of 2) where the Hg2(2+) ion linearly bridges two Co(dppea) fragments.The dppea derivative reacts with carbon monoxide or carbon dioxide, at room temperature and atmospheric pressure, with formation of the carbonyl complex BPh4.

Reactivity of [N(CH2CH2PPh2)3]CoH toward CS2, SCNPh, OCNPh, and COS

Bianchini, Claudio,Meli, Andrea,Scapacci, Giancarlo

, p. 1834 - 1838 (2008/10/08)

Reaction of (np3)CoH (1) [np3 = tris[2-(diphenylphosphino)ethyl]amine] with CS2, SCNPh, or OCNPh affords (np3)Co(η2-CS2) (2), (np3)Co(η2-SCNPh) (6), and (np3)Co(η2-OCNPh) (8), respectively. In the presence of NaBPh4 1 reacts with CS2 or SCNPh to give [(np3)Co(CS)]BPh4 (3) and [(np3)Co(CNPh)]BPh4 (7), respectively, and with OCNPh or COS to give [(np3)Co(CO)]BPh4 (4). Methylation of 2 by MeSO3F, followed by NaBPh4 addition, leads to [Ph2PCH2CH2N(CH2CH 2PPh2)2Co(CS2Me)]BPh4 (5) through intramolecular attack by a phosphorus atom of np3 on a formed in situ η2-dithiomethyl ester group. On reaction of 5 with NaBH4 the P-CS2Me and C-SMe bonds are cleaved and the thiocarbonyl complex 3 is formed.

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