54353-77-4Relevant academic research and scientific papers
Deracemization of axially chiral α,β-unsaturated aldehydes through an amino-catalyzed symmetry-making-symmetry-breaking cascade
Jiang, Hao,Halskov, Kim Soholm,Johansen, Tore Kiilerich,Jorgensen, Karl Anker
supporting information; experimental part, p. 3842 - 3846 (2011/05/07)
Highly enantioenriched products have been prepared in good yields from racemic enal starting materials through a new deracemization strategy that employs an enantioconvergent amino-catalyzed symmetry-making-symmetry-breaking cascade. The reaction design features the tandem domination of product development and catalyst control in two reaction steps (see scheme).
Circular Dichroism of Linearly Conjugated Chromophores
Gawronski, J. K.,Walborsky, H. M.
, p. 2863 - 2870 (2007/10/02)
A series of chiral four to eight ?-electron systems of planar linearly conjugated systems has been prepared, and their chiroptical properties have been determined.The effect of changes in both configuration and conformation on the circular dichroism spect
