7071-18-3

Upstream product

• 5108-88-3 ethyl (1-hydroxy-4-methylcyclohexyl)acetate 
• 23985-32-2 (Ξ)-4-Methyl-1-vinyl-cyclohexanol 
• 77842-31-0 (4-methylcyclohexylidene)acetic acid 
• 589-92-4 1-methylcyclohexan-4-one 
• 127180-76-1 ethyl 4-methylcyclohexylideneacetate 
• 54353-77-4 (aS)-(4-methylcyclohexylidene)acetonitrile 
• 56300-87-9 2-(4-Methylcyclohexyliden)-ethanol 
• 7014-73-5 1-Brom-2-<4-methyl-cyclohexyliden>-aethan 

Downstream Products

• 102633-36-3 ethyl (Z)-4-((aS)-4-methylcyclohexylidene)-2-butenoate 
• 102633-35-2 ethyl (E)-4-((aS)-4-methylcyclohexylidene)-2-butenoate 
• 102633-55-6 anti (aS)-(4-methylcyclohexylidene)acetaldehyde oxime 
• 102633-56-7 syn (aS)-(4-methylcyclohexylidene)acetaldehyde oxime 
• 102633-40-9 (Z)-5-((aS)-4-methylcyclohexylidene)-1,3-pentadiene 
• 102633-39-6 (E)-5-((aS)-4-methylcyclohexylidene)-1,3-pentadiene 
• 102633-51-2 (Z)-4-((aS)-4-methylcyclohexylidene)-2-buten-1-ol 
• 102633-50-1 (E)-4-((aS)-4-methylcyclohexylidene)-2-buten-1-ol 
• 102633-31-8 (Z)-4-((aS)-4-methylcyclohexylidene)-2-buten-1-on 
• 102633-30-7 (E)-4-((aS)-4-methylcyclohexylidene)-2-buten-1-on 
• 102633-44-3 ethyl (2Z,4Z)-6-((aS)-4-methylcyclohexylidene)-2,4-hexadienoate 
• 102633-43-2 ethyl (2E,4Z)-6-((aS)-4-methylcyclohexylidene)-2,4-hexadienoate 
• 102633-42-1 ethyl (2Z,4E)-6-((aS)-4-methylcyclohexylidene)-2,4-hexadienoate 
• 102633-41-0 ethyl (2E,4E)-6-((aS)-4-methylcyclohexylidene)-2,4-hexadienoate 

Relevant academic research and scientific papers

Deracemization of axially chiral α,β-unsaturated aldehydes through an amino-catalyzed symmetry-making-symmetry-breaking cascade

Highly enantioenriched products have been prepared in good yields from racemic enal starting materials through a new deracemization strategy that employs an enantioconvergent amino-catalyzed symmetry-making-symmetry-breaking cascade. The reaction design features the tandem domination of product development and catalyst control in two reaction steps (see scheme).