543690-03-5

Basic information

• Product Name: C₁₅H₁₈O₄
• CAS NO: 543690-03-5
• Molecular Weight: 262.306
• Mol File: 543690-03-5.mol

Chemical Properties

• CAS DataBase Reference: C₁₅H₁₈O₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₁₈O₄(543690-03-5)
• EPA Substance Registry System: C₁₅H₁₈O₄(543690-03-5)

Safety Data

• Hazardous Substances Data: 543690-03-5(Hazardous Substances Data)

Upstream product

• 952686-35-0 methyl p-methylphenylallyl carbonate 
• 108-59-8 malonic acid dimethyl ester 

Relevant articles and documents

Iridium/ N-Heterocyclic Carbene Complex-Catalyzed Intermolecular Allylic Alkylation Reaction

N-Heterocyclic carbenes (NHCs) were found to be suitable ligands in Ir-catalyzed intermolecular allylic alkylation reaction. In the presence of a catalyst derived from [Ir(dncot)Cl]2 (dncot = dinaphthocyclooctatetraene) and triazolium salt L7,

Bis(perfluoroalkyl) phosphino-oxazoline: A modular, stable, strongly π-accepting ligand for asymmetric catalysis

A new class of stable, strongly π-accepting and modular bis-(perfluoroalkyl)-phosphine-oxazoline ligands (FOX) as CO mimics was prepared. It was demonstrated that these ligands, when coordinated to palladium catalysts, promote the asymmetric alkylation of monosubstituted allyl substrates with excellent regio- and enantioselectivity. Solid and solution structure analysis of the FOX-ligated Pd-allyl intermediate reveals that the combination of relative steric and strong trans influences presented by the P(CF 3)2 moiety gave rise to the excellent selectivity.