543724-50-1

Basic information

• Product Name: 4-(tert-butyldiphenylsilyloxy)cyclohex-2-enone
• Synonyms: 4-(tert-butyldiphenylsilyloxy)cyclohex-2-enone
• CAS NO: 543724-50-1
• Molecular Weight: 350.533
• Mol File: 543724-50-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-(tert-butyldiphenylsilyloxy)cyclohex-2-enone(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(tert-butyldiphenylsilyloxy)cyclohex-2-enone(543724-50-1)
• EPA Substance Registry System: 4-(tert-butyldiphenylsilyloxy)cyclohex-2-enone(543724-50-1)

Safety Data

• Hazardous Substances Data: 543724-50-1(Hazardous Substances Data)

Upstream product

• 952589-06-9 (1R,4R)-4-((tert-butyldiphenylsilyl)oxy)cyclohexanol 
• 543724-48-7 tert-butyl-(1,4-dioxa-spiro[4.5]dec-8-yloxy)-diphenyl-silane 
• 130745-59-4 4-<(tert-Butyldiphenylsilyl)oxy>cyclohexanone 
• 4746-97-8 cyclohexanedione monoethylene ketal 
• 22428-87-1 4,4-ethylenedioxycyclohexan-1-ol 

Downstream Products

• 543724-55-6 3-(tert-butyl-diphenyl-silanyloxy)-6-hept-6-enylidene-cyclohex-1-enecarbaldehyde 
• 543724-54-5 (3-bromo-4-hept-6-enylidene-cyclohex-2-enyloxy)-tert-butyl-diphenyl-silane 
• 543724-51-2 2-bromo-4-(tert-butyl-diphenyl-silanyloxy)-cyclohex-2-enone 

Relevant articles and documents

METHOD FOR PRODUCING CARBONYL COMPOUND AN PRO-OXIDANT USED FOR PRODUCTION OF CARBONYL COMPOUND

The invention provides a process for the preparation of a carbonyl compound in high efficiency by oxidizing an alcohol. The process for the preparation of a carbonyl compound of the present invention includes a step of oxidizing an alcohol in the presence of a compound of the formula (I) or a derivative or a salt thereof, and an oxidant, wherein R1 and R2 independently represent hydrogen, a halogen, a nitro or acidic group, or an alkyl or alkoxy group, each of which optionally has a substituent, or R1 and R2 combine the two carbon atoms to which they are boned to form an aromatic ring.

A diene-transmissive approach to the quassinoid skeleton

Several tetracyclic molecules were prepared by diene-transmissive Diels-Alder cycloadditions. Control over the stereochemical outcome of the cycloaddition was achieved and the structural features of the precursors affecting the stereochemistry is discussed. Useful information was gathered concerning the factors governing this stereocontrol, which will be indispensable for the future of this strategy.