54394-61-5Relevant academic research and scientific papers
Highly enantioselective iridium-catalysed allylic aminations with anionic N-nucleophiles
Weihofen, Robert,Dahnz, Axel,Tverskoy, Olena,Helmchen, Guenter
, p. 3541 - 3543 (2007/10/03)
Iridium-catalysed allylic substitutions with anionic N-nucleophiles were achieved with regioselectivity of up to 49:1 and enantiomeric excess of up to 98%. The Royal Society of Chemistry 2005.
Hydroamination of alkynes catalyzed by palladium/benzoic acid
Lutete, Leopold Mpaka,Kadota, Isao,Shibuya, Akinori,Yamamoto, Yoshinori
, p. 347 - 357 (2007/10/03)
The reaction of internal alkynes (1) with amines (2) in the presence of catalytic amount of Pd(PPh3)4 and benzoic acid in dioxane at 100°C gave the allylic amines (3) in good to excellent yields. The intramolecular reaction of alkyne
