171037-07-3

Upstream product

• 160879-62-9 methyl 1-phenylprop-2-enyl carbonate 
• 108-95-2 phenol 
• 100-46-9 benzylamine 
• 100-52-7 benzaldehyde 
• 104713-12-4 (1S)-1-phenylprop-2-en-1-ol 
• 79-22-1 methyl chloroformate 

Downstream Products

• 54394-61-5 N-benzyl-N-[(E)-3-phenyl-2-propenyl]tosylamide 
• 87802-78-6 dimethyl (S)-2-(1-phenylallyl)malonate 
• 164713-27-3 dimethyl 2-((R)-1-phenylallyl)malonate 
• 255043-88-0 (1R)-1-(phenylprop-2-enyl)-(1S)-1-[(phenylmethoxy)methyl]prop-2-enyl-[(4-methylphenyl)sulfonyl]amine 
• 255043-89-1 C₂₇H₂₉NO₃S 
• 119793-72-5 (E)-2-(3-phenyl-allyl) malonic acid dimethyl ester 

Relevant academic research and scientific papers

Readily Available [2.2.2]-Bicyclooctadienes as New Chiral Ligands for Ir(I): Catalytic, Kinetic Resolution of Allyl Carbonates

We report an Ir(I)-catalyzed kinetic resolution of secondary allylic carbonates allowing for their isolation in up to 98% ee. Importantly, the study documents the synthesis and use of a new class of chiral [2.2.2]-bicyclooctadiene ligands for iridium. Cop

Substituent effects on the amination of racemic allyl carbonates using commercially available chiral rhodium catalysts

In the presence of commercially available chiral rhodium catalysts, a competitive benzy lamination of racemic allyl carbonates, substituted with p-X-Ph groups, shows that the reaction proceeds faster with substituents (X) that are more electron-withdrawing. Mechanistic implications of these results are discussed.

Regiocontrol and Stereoselectivity in Tungsten-Bipyridine Catalysed Allylic Alkylation

Tungsten-bipyridine complexes, generated in situ, catalyse the allylic alkylation of isocinnamyl methyl carbonate by dimethyl sodiomalonate with complete syn-stereoselectivity.When para substituted aryl-allyl methyl carbonates are employed, the regioselectivity correlates with Swain-Lupton parameters.Cross-over experiments demonstrate that the reactions do not proceed via the conventional 0> -> II allyl>+ -> 0 allyl-Nu> catalytic cycle.