54419-95-3Relevant academic research and scientific papers
Photoinduced reactions of chloroacetone in solid Ar: Identification of CH2=COClCH3
Tanaka, Nobuaki,Urashima, Yoshitaka,Nishikiori, Hiromasa
, p. 258 - 262 (2014)
The UV light-induced reactions of chloroacetone in a cryogenic Ar matrix were investigated using infrared spectroscopy. The photoinduced isomerisations of gauche-chloroacetone to syn-chloroacetone and hypochlorous acid 1-methylethenyl ester were confirmed by comparing the experimental and calculated spectra. In addition, the photolysis products were found to be CH2CO and a cyclopropanone-HCl complex. The cyclopropanone-HCl complex was further decomposed into CH2CH2, CO and HCl. The hypochlorous acid 1-methylethenyl ester was further isomerized to 2-chloro-2-methyloxirane.
Hg(3P) Photosensitized Chemistry of Ethyl Halides in Krypton Matrix
Cartland, Harry E.,Pimentel, George C.
, p. 8021 - 8025 (2007/10/02)
The reaction of Hg atoms in the 3P state with the ethyl halides is studied in krypton matrix.The primary products result from molecular elimination, though the behavior of ethyl fluoride is different from that of ethyl chloride and bromide in that H2 elimination is observed exclusively rather than the hydrogen halide elimination that predominates for the other ethyl halides.Some insertion of Hg into C-Cl and C-Br bonds occurs, a process absent in the gas-phase photochemistry.
