54445-55-5Relevant academic research and scientific papers
Vinylogous Wolff Rearrangement. 4. General Reaction of β,γ-Unsaturated α'-Diazo Ketones
Smith, Amos B.,Toder, Bruce H.,Branca, Stephen J.
, p. 3995 - 4001 (2007/10/02)
The preparation and vinylogous Wolff rearrangement (VWR) of some 21 acyclic and monocyclic β,γ-unsaturated α'-diazo ketones are described.The resulting γ,δ-unsaturated esters are summarized in Tables I-VI.The rearrangement is promoted by CuSO4, Cu(AcAc)2,
